Cargando…

[2,6-Bis(6-methyl­quinolin-2-yl)pyridine-κ(3) N,N′,N′′]dichloridomanganese(II)

In the mol­ecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudor...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Xiao-Ping, Zhao, Jian-She, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983179/
https://www.ncbi.nlm.nih.gov/pubmed/21587437
http://dx.doi.org/10.1107/S1600536810037037
Descripción
Sumario:In the mol­ecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak inter­molecular C—H⋯Cl hydrogen bonding occurs in the crystal structure.