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[2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3) N,N′,N′′]dichloridomanganese(II)
In the molecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudor...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983179/ https://www.ncbi.nlm.nih.gov/pubmed/21587437 http://dx.doi.org/10.1107/S1600536810037037 |
Sumario: | In the molecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak intermolecular C—H⋯Cl hydrogen bonding occurs in the crystal structure. |
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