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catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a dis...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983181/ https://www.ncbi.nlm.nih.gov/pubmed/21587385 http://dx.doi.org/10.1107/S1600536810035452 |
Sumario: | The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL (−) and three L (2−) ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L (2−) ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H⋯O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains. |
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