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Tri-μ-sulfato-κ(6) O:O′-bis[aqua(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water molecule and three sulfate O atoms in a distorted InN(2)O(4) octahedral geometry. Three sulfate anions bridge two In(III...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983182/ https://www.ncbi.nlm.nih.gov/pubmed/21587408 http://dx.doi.org/10.1107/S1600536810036330 |
Sumario: | In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water molecule and three sulfate O atoms in a distorted InN(2)O(4) octahedral geometry. Three sulfate anions bridge two In(III) cations, forming the dinuclear entities. O—H⋯O and weak C—H⋯O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π–π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid–centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å. |
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