Cargando…

Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate

In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water mol­ecule and three sulfate O atoms in a distorted InN(2)O(4) octa­hedral geometry. Three sulfate anions bridge two In(III...

Descripción completa

Detalles Bibliográficos
Autores principales: Shen, Fwu Ming, Lush, Shie Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983182/
https://www.ncbi.nlm.nih.gov/pubmed/21587408
http://dx.doi.org/10.1107/S1600536810036330
_version_ 1782191820180029440
author Shen, Fwu Ming
Lush, Shie Fu
author_facet Shen, Fwu Ming
Lush, Shie Fu
author_sort Shen, Fwu Ming
collection PubMed
description In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water mol­ecule and three sulfate O atoms in a distorted InN(2)O(4) octa­hedral geometry. Three sulfate anions bridge two In(III) cations, forming the dinuclear entities. O—H⋯O and weak C—H⋯O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π–π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid–centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å.
format Text
id pubmed-2983182
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29831822010-12-30 Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate Shen, Fwu Ming Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water mol­ecule and three sulfate O atoms in a distorted InN(2)O(4) octa­hedral geometry. Three sulfate anions bridge two In(III) cations, forming the dinuclear entities. O—H⋯O and weak C—H⋯O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π–π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid–centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983182/ /pubmed/21587408 http://dx.doi.org/10.1107/S1600536810036330 Text en © Shen and Lush 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Fwu Ming
Lush, Shie Fu
Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
title Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
title_full Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
title_fullStr Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
title_full_unstemmed Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
title_short Tri-μ-sulfato-κ(6) O:O′-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
title_sort tri-μ-sulfato-κ(6) o:o′-bis­[aqua­(1,10-phenanthroline-κ(2) n,n′)indium(iii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983182/
https://www.ncbi.nlm.nih.gov/pubmed/21587408
http://dx.doi.org/10.1107/S1600536810036330
work_keys_str_mv AT shenfwuming trimsulfatok6oobisaqua110phenanthrolinek2nnindiumiiidihydrate
AT lushshiefu trimsulfatok6oobisaqua110phenanthrolinek2nnindiumiiidihydrate