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Tri-μ-sulfato-κ(6) O:O′-bis[aqua(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate
In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water molecule and three sulfate O atoms in a distorted InN(2)O(4) octahedral geometry. Three sulfate anions bridge two In(III...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983182/ https://www.ncbi.nlm.nih.gov/pubmed/21587408 http://dx.doi.org/10.1107/S1600536810036330 |
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author | Shen, Fwu Ming Lush, Shie Fu |
author_facet | Shen, Fwu Ming Lush, Shie Fu |
author_sort | Shen, Fwu Ming |
collection | PubMed |
description | In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water molecule and three sulfate O atoms in a distorted InN(2)O(4) octahedral geometry. Three sulfate anions bridge two In(III) cations, forming the dinuclear entities. O—H⋯O and weak C—H⋯O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π–π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid–centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å. |
format | Text |
id | pubmed-2983182 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831822010-12-30 Tri-μ-sulfato-κ(6) O:O′-bis[aqua(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate Shen, Fwu Ming Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water molecule and three sulfate O atoms in a distorted InN(2)O(4) octahedral geometry. Three sulfate anions bridge two In(III) cations, forming the dinuclear entities. O—H⋯O and weak C—H⋯O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π–π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid–centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983182/ /pubmed/21587408 http://dx.doi.org/10.1107/S1600536810036330 Text en © Shen and Lush 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shen, Fwu Ming Lush, Shie Fu Tri-μ-sulfato-κ(6) O:O′-bis[aqua(1,10-phenanthroline-κ(2) N,N′)indium(III)] dihydrate |
title | Tri-μ-sulfato-κ(6)
O:O′-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)indium(III)] dihydrate |
title_full | Tri-μ-sulfato-κ(6)
O:O′-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)indium(III)] dihydrate |
title_fullStr | Tri-μ-sulfato-κ(6)
O:O′-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)indium(III)] dihydrate |
title_full_unstemmed | Tri-μ-sulfato-κ(6)
O:O′-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)indium(III)] dihydrate |
title_short | Tri-μ-sulfato-κ(6)
O:O′-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)indium(III)] dihydrate |
title_sort | tri-μ-sulfato-κ(6)
o:o′-bis[aqua(1,10-phenanthroline-κ(2)
n,n′)indium(iii)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983182/ https://www.ncbi.nlm.nih.gov/pubmed/21587408 http://dx.doi.org/10.1107/S1600536810036330 |
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