Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)

In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra­coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl­diazen­yl]-2-naphtho­late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are...

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Detalles Bibliográficos
Autores principales: Tai, Wan-Ju, Li, Chi-Huan, Li, Chen-Yu, Ko, Bao-Tsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983183/
https://www.ncbi.nlm.nih.gov/pubmed/21587451
http://dx.doi.org/10.1107/S1600536810037888
Descripción
Sumario:In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra­coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl­diazen­yl]-2-naphtho­late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, with an O—Cu—O bond angle of 177.00 (9)° and an N—Cu—N bond angle of 165.63 (10)°. The average distances between the Cu(II) atom and the coordinated O and N atoms are 1.905 (2) and 1.995 (2)Å, respectively.

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