Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)

In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra­coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl­diazen­yl]-2-naphtho­late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are...

Descripción completa

Detalles Bibliográficos
Autores principales: Tai, Wan-Ju, Li, Chi-Huan, Li, Chen-Yu, Ko, Bao-Tsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983183/
https://www.ncbi.nlm.nih.gov/pubmed/21587451
http://dx.doi.org/10.1107/S1600536810037888
_version_ 1782191820418056192
author Tai, Wan-Ju
Li, Chi-Huan
Li, Chen-Yu
Ko, Bao-Tsan
author_facet Tai, Wan-Ju
Li, Chi-Huan
Li, Chen-Yu
Ko, Bao-Tsan
author_sort Tai, Wan-Ju
collection PubMed
description In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra­coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl­diazen­yl]-2-naphtho­late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, with an O—Cu—O bond angle of 177.00 (9)° and an N—Cu—N bond angle of 165.63 (10)°. The average distances between the Cu(II) atom and the coordinated O and N atoms are 1.905 (2) and 1.995 (2)Å, respectively.
format Text
id pubmed-2983183
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29831832010-12-30 Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II) Tai, Wan-Ju Li, Chi-Huan Li, Chen-Yu Ko, Bao-Tsan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(17)H(13)N(2)O)(2)], the Cu(II) atom is tetra­coordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyl­diazen­yl]-2-naphtho­late ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the Cu(II) atom are trans to each other, with an O—Cu—O bond angle of 177.00 (9)° and an N—Cu—N bond angle of 165.63 (10)°. The average distances between the Cu(II) atom and the coordinated O and N atoms are 1.905 (2) and 1.995 (2)Å, respectively. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983183/ /pubmed/21587451 http://dx.doi.org/10.1107/S1600536810037888 Text en © Tai et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tai, Wan-Ju
Li, Chi-Huan
Li, Chen-Yu
Ko, Bao-Tsan
Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)
title Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)
title_full Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)
title_fullStr Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)
title_full_unstemmed Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)
title_short Bis{1-[(E)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(II)
title_sort bis{1-[(e)-o-tolyl­diazen­yl]-2-naphtho­l­ato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983183/
https://www.ncbi.nlm.nih.gov/pubmed/21587451
http://dx.doi.org/10.1107/S1600536810037888
work_keys_str_mv AT taiwanju bis1eotolyldiazenyl2naphtholatocopperii
AT lichihuan bis1eotolyldiazenyl2naphtholatocopperii
AT lichenyu bis1eotolyldiazenyl2naphtholatocopperii
AT kobaotsan bis1eotolyldiazenyl2naphtholatocopperii

Ejemplares similares