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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octahedral coordination geometry. The oxalate anions act as bis-bidentate ligand...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983185/ https://www.ncbi.nlm.nih.gov/pubmed/21587384 http://dx.doi.org/10.1107/S1600536810035440 |
Sumario: | In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octahedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu–phen units in zigzag chains extending parallel to [100]. Interchain C—H⋯O hydrogen bonding and π–π stacking interactions [centroid–centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supramolecular network. |
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