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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]

In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa­hedral coordination geometry. The oxalate anions act as bis-bidentate ligand...

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Detalles Bibliográficos
Autores principales: Wang, Jun, Hou, Yong, Fang, Zhi-li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983185/
https://www.ncbi.nlm.nih.gov/pubmed/21587384
http://dx.doi.org/10.1107/S1600536810035440
Descripción
Sumario:In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa­hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu–phen units in zigzag chains extending parallel to [100]. Inter­chain C—H⋯O hydrogen bonding and π–π stacking inter­actions [centroid–centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supra­molecular network.