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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]

In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa­hedral coordination geometry. The oxalate anions act as bis-bidentate ligand...

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Detalles Bibliográficos
Autores principales: Wang, Jun, Hou, Yong, Fang, Zhi-li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983185/
https://www.ncbi.nlm.nih.gov/pubmed/21587384
http://dx.doi.org/10.1107/S1600536810035440
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author Wang, Jun
Hou, Yong
Fang, Zhi-li
author_facet Wang, Jun
Hou, Yong
Fang, Zhi-li
author_sort Wang, Jun
collection PubMed
description In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa­hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu–phen units in zigzag chains extending parallel to [100]. Inter­chain C—H⋯O hydrogen bonding and π–π stacking inter­actions [centroid–centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supra­molecular network.
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spelling pubmed-29831852010-12-30 catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] Wang, Jun Hou, Yong Fang, Zhi-li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa­hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu–phen units in zigzag chains extending parallel to [100]. Inter­chain C—H⋯O hydrogen bonding and π–π stacking inter­actions [centroid–centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supra­molecular network. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983185/ /pubmed/21587384 http://dx.doi.org/10.1107/S1600536810035440 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jun
Hou, Yong
Fang, Zhi-li
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
title catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
title_full catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
title_fullStr catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
title_short catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
title_sort catena-poly[[(1,10-phenanthroline)copper(ii)]-μ-oxalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983185/
https://www.ncbi.nlm.nih.gov/pubmed/21587384
http://dx.doi.org/10.1107/S1600536810035440
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