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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octahedral coordination geometry. The oxalate anions act as bis-bidentate ligand...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983185/ https://www.ncbi.nlm.nih.gov/pubmed/21587384 http://dx.doi.org/10.1107/S1600536810035440 |
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author | Wang, Jun Hou, Yong Fang, Zhi-li |
author_facet | Wang, Jun Hou, Yong Fang, Zhi-li |
author_sort | Wang, Jun |
collection | PubMed |
description | In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octahedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu–phen units in zigzag chains extending parallel to [100]. Interchain C—H⋯O hydrogen bonding and π–π stacking interactions [centroid–centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2983185 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831852010-12-30 catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] Wang, Jun Hou, Yong Fang, Zhi-li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octahedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu–phen units in zigzag chains extending parallel to [100]. Interchain C—H⋯O hydrogen bonding and π–π stacking interactions [centroid–centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supramolecular network. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983185/ /pubmed/21587384 http://dx.doi.org/10.1107/S1600536810035440 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Jun Hou, Yong Fang, Zhi-li catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] |
title |
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] |
title_full |
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] |
title_fullStr |
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] |
title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] |
title_short |
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato] |
title_sort | catena-poly[[(1,10-phenanthroline)copper(ii)]-μ-oxalato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983185/ https://www.ncbi.nlm.nih.gov/pubmed/21587384 http://dx.doi.org/10.1107/S1600536810035440 |
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