catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]

The title chain polymer compound, [GaLi(2)Br(C(3)H(9)OSi)(4)(C(4)H(8)O)(2)](n), was obtained in the reaction of GaBr(3) with Me(3)SiOLi in toluene/tetra­hydro­furan. The Ga(III) atom, located on a twofold rotation axis, is coordinated by four trimethyl­silanolate ligands and has a distorted tetra­he...

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Detalles Bibliográficos
Autores principales: Grubba, Rafał, Baranowska, Katarzyna, Pikies, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983186/
https://www.ncbi.nlm.nih.gov/pubmed/21587392
http://dx.doi.org/10.1107/S1600536810035518
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author Grubba, Rafał
Baranowska, Katarzyna
Pikies, Jerzy
author_facet Grubba, Rafał
Baranowska, Katarzyna
Pikies, Jerzy
author_sort Grubba, Rafał
collection PubMed
description The title chain polymer compound, [GaLi(2)Br(C(3)H(9)OSi)(4)(C(4)H(8)O)(2)](n), was obtained in the reaction of GaBr(3) with Me(3)SiOLi in toluene/tetra­hydro­furan. The Ga(III) atom, located on a twofold rotation axis, is coordinated by four trimethyl­silanolate ligands and has a distorted tetra­hedral geometry. The Li(I) atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethyl­silanolate ligands and one tetra­hydro­furane mol­ecule in a distorted tetra­hedral geometry. The polymeric chains extend along [001]. The tetra­hydro­furane mol­ecule is disordered over two positions with site-occupancy factors of 0.57 (2) and 0.43 (2).
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spelling pubmed-29831862010-12-30 catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido] Grubba, Rafał Baranowska, Katarzyna Pikies, Jerzy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title chain polymer compound, [GaLi(2)Br(C(3)H(9)OSi)(4)(C(4)H(8)O)(2)](n), was obtained in the reaction of GaBr(3) with Me(3)SiOLi in toluene/tetra­hydro­furan. The Ga(III) atom, located on a twofold rotation axis, is coordinated by four trimethyl­silanolate ligands and has a distorted tetra­hedral geometry. The Li(I) atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethyl­silanolate ligands and one tetra­hydro­furane mol­ecule in a distorted tetra­hedral geometry. The polymeric chains extend along [001]. The tetra­hydro­furane mol­ecule is disordered over two positions with site-occupancy factors of 0.57 (2) and 0.43 (2). International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983186/ /pubmed/21587392 http://dx.doi.org/10.1107/S1600536810035518 Text en © Grubba et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Grubba, Rafał
Baranowska, Katarzyna
Pikies, Jerzy
catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]
title catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]
title_full catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]
title_fullStr catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]
title_full_unstemmed catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]
title_short catena-Poly[[(tetra­hydro­furan-κO)lithium(I)]-bis­(μ-trimethyl­silanolato-κ(2) O:O)-gallium(III)-bis­(μ-trimethyl­silanolato-κ(2) O:O)-[(tetra­hydro­furan-κO)lithium(I)]-μ-bromido]
title_sort catena-poly[[(tetra­hydro­furan-κo)lithium(i)]-bis­(μ-trimethyl­silanolato-κ(2) o:o)-gallium(iii)-bis­(μ-trimethyl­silanolato-κ(2) o:o)-[(tetra­hydro­furan-κo)lithium(i)]-μ-bromido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983186/
https://www.ncbi.nlm.nih.gov/pubmed/21587392
http://dx.doi.org/10.1107/S1600536810035518
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AT baranowskakatarzyna catenapolytetrahydrofurankolithiumibismtrimethylsilanolatok2oogalliumiiibismtrimethylsilanolatok2ootetrahydrofurankolithiumimbromido
AT pikiesjerzy catenapolytetrahydrofurankolithiumibismtrimethylsilanolatok2oogalliumiiibismtrimethylsilanolatok2ootetrahydrofurankolithiumimbromido

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