catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]

In the title complex, {[Cu(C(12)H(12)O(4))(C(5)H(5)N)(2)]·H(2)O}(n), the Cu(II) ion lies on an inversion center and is coordinated by two O atoms from two 2,3,5,6-tetra­methyl­benzene-1,4-dicarboxyl­ate (TBDC) ligands and two N atoms from two pyridine ligands in a slightly distorted square-planar en...

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Detalles Bibliográficos
Autor principal: Hu, Xiaoqin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983187/
https://www.ncbi.nlm.nih.gov/pubmed/21587440
http://dx.doi.org/10.1107/S1600536810036913
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author Hu, Xiaoqin
author_facet Hu, Xiaoqin
author_sort Hu, Xiaoqin
collection PubMed
description In the title complex, {[Cu(C(12)H(12)O(4))(C(5)H(5)N)(2)]·H(2)O}(n), the Cu(II) ion lies on an inversion center and is coordinated by two O atoms from two 2,3,5,6-tetra­methyl­benzene-1,4-dicarboxyl­ate (TBDC) ligands and two N atoms from two pyridine ligands in a slightly distorted square-planar environment. The TBDC ligands act as bridging ligands, forming chains along [110]. These chains are further linked into a two-dimensional network via inter­molecular O—H⋯O hydrogen bonds. The solvent water mol­ecule lies on a twofold rotation axis.
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spelling pubmed-29831872010-12-30 catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate] Hu, Xiaoqin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(C(12)H(12)O(4))(C(5)H(5)N)(2)]·H(2)O}(n), the Cu(II) ion lies on an inversion center and is coordinated by two O atoms from two 2,3,5,6-tetra­methyl­benzene-1,4-dicarboxyl­ate (TBDC) ligands and two N atoms from two pyridine ligands in a slightly distorted square-planar environment. The TBDC ligands act as bridging ligands, forming chains along [110]. These chains are further linked into a two-dimensional network via inter­molecular O—H⋯O hydrogen bonds. The solvent water mol­ecule lies on a twofold rotation axis. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983187/ /pubmed/21587440 http://dx.doi.org/10.1107/S1600536810036913 Text en © Xiaoqin Hu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Xiaoqin
catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
title catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
title_full catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
title_fullStr catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
title_full_unstemmed catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
title_short catena-Poly[[[dipyridine­copper(II)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
title_sort catena-poly[[[dipyridine­copper(ii)]-μ-2,3,5,6-tetra­methyl­benzene-1,4-di­carboxyl­ato] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983187/
https://www.ncbi.nlm.nih.gov/pubmed/21587440
http://dx.doi.org/10.1107/S1600536810036913
work_keys_str_mv AT huxiaoqin catenapolydipyridinecopperiim2356tetramethylbenzene14dicarboxylatomonohydrate

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