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9-(1,1-Dimethyl-3-oxobut­yl)adenine

The title compound, C(11)H(15)N(5)O, crystallizes with two independent mol­ecules in the asymmetric unit, both of which contain essentially planar imidazole and pyrimidine rings [maximum deviations = 0.002 (2) and 0.026 (2) Å, respectively, for the first mol­ecule, and 0.001 (2) and 0.025 (2) Å for...

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Detalles Bibliográficos
Autores principales: Kong, Dulin, Wu, Mingshu, Li, Huiyan, Ma, Jingya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983190/
https://www.ncbi.nlm.nih.gov/pubmed/21587476
http://dx.doi.org/10.1107/S1600536810034628
Descripción
Sumario:The title compound, C(11)H(15)N(5)O, crystallizes with two independent mol­ecules in the asymmetric unit, both of which contain essentially planar imidazole and pyrimidine rings [maximum deviations = 0.002 (2) and 0.026 (2) Å, respectively, for the first mol­ecule, and 0.001 (2) and 0.025 (2) Å for the second]; the dihedral angles between the rings are 2.1 (2) and 1.7 (2)° in the two mol­ecules. The crystal structure is stabilized by inter­molecular N—H⋯N hydrogen bonds, defining chains along a, which are further linked by weak inter­molecular π–π contacts [centroid centroid distance = 3.7989 (16) Å] into planes parallel to (01[Image: see text]).