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9-(1,1-Dimethyl-3-oxobutyl)adenine
The title compound, C(11)H(15)N(5)O, crystallizes with two independent molecules in the asymmetric unit, both of which contain essentially planar imidazole and pyrimidine rings [maximum deviations = 0.002 (2) and 0.026 (2) Å, respectively, for the first molecule, and 0.001 (2) and 0.025 (2) Å for...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983190/ https://www.ncbi.nlm.nih.gov/pubmed/21587476 http://dx.doi.org/10.1107/S1600536810034628 |
Sumario: | The title compound, C(11)H(15)N(5)O, crystallizes with two independent molecules in the asymmetric unit, both of which contain essentially planar imidazole and pyrimidine rings [maximum deviations = 0.002 (2) and 0.026 (2) Å, respectively, for the first molecule, and 0.001 (2) and 0.025 (2) Å for the second]; the dihedral angles between the rings are 2.1 (2) and 1.7 (2)° in the two molecules. The crystal structure is stabilized by intermolecular N—H⋯N hydrogen bonds, defining chains along a, which are further linked by weak intermolecular π–π contacts [centroid centroid distance = 3.7989 (16) Å] into planes parallel to (01[Image: see text]). |
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