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[2,6-Bis(p-tolyliminomethyl)pyridine-κ(3) N,N′,N′′]dichloridocopper(II)
The title compound, [CuCl(2)(C(21)H(19)N(3))], lies on a twofold rotation axis that passes through the N(pyridyl)—Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial–equatorial–axial sites of the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983193/ https://www.ncbi.nlm.nih.gov/pubmed/21587436 http://dx.doi.org/10.1107/S1600536810037025 |
| Sumario: | The title compound, [CuCl(2)(C(21)H(19)N(3))], lies on a twofold rotation axis that passes through the N(pyridyl)—Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu(II) atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). |
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