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[2,6-Bis(p-tolyliminomethyl)pyridine-κ(3) N,N′,N′′]dichloridocopper(II)
The title compound, [CuCl(2)(C(21)H(19)N(3))], lies on a twofold rotation axis that passes through the N(pyridyl)—Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial–equatorial–axial sites of the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983193/ https://www.ncbi.nlm.nih.gov/pubmed/21587436 http://dx.doi.org/10.1107/S1600536810037025 |
| _version_ | 1782191822796226560 |
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| author | Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng |
| author_facet | Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng |
| author_sort | Li, Xiao-Ping |
| collection | PubMed |
| description | The title compound, [CuCl(2)(C(21)H(19)N(3))], lies on a twofold rotation axis that passes through the N(pyridyl)—Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu(II) atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). |
| format | Text |
| id | pubmed-2983193 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29831932010-12-30 [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3) N,N′,N′′]dichloridocopper(II) Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuCl(2)(C(21)H(19)N(3))], lies on a twofold rotation axis that passes through the N(pyridyl)—Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu(II) atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983193/ /pubmed/21587436 http://dx.doi.org/10.1107/S1600536810037025 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3) N,N′,N′′]dichloridocopper(II) |
| title | [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3)
N,N′,N′′]dichloridocopper(II) |
| title_full | [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3)
N,N′,N′′]dichloridocopper(II) |
| title_fullStr | [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3)
N,N′,N′′]dichloridocopper(II) |
| title_full_unstemmed | [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3)
N,N′,N′′]dichloridocopper(II) |
| title_short | [2,6-Bis(p-tolyliminomethyl)pyridine-κ(3)
N,N′,N′′]dichloridocopper(II) |
| title_sort | [2,6-bis(p-tolyliminomethyl)pyridine-κ(3)
n,n′,n′′]dichloridocopper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983193/ https://www.ncbi.nlm.nih.gov/pubmed/21587436 http://dx.doi.org/10.1107/S1600536810037025 |
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