{6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)

In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom has a slightly distorted square-planar coordination environment. The dihedral angles between the central benzene ring and the two outer rings are 7.62 (16) and 9.78 (17)°. The crystal structure is stabilized by inter­molecul...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz, Sahraei, Atefeh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983194/
https://www.ncbi.nlm.nih.gov/pubmed/21587396
http://dx.doi.org/10.1107/S1600536810035890
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author Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
Sahraei, Atefeh
author_facet Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
Sahraei, Atefeh
author_sort Kargar, Hadi
collection PubMed
description In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom has a slightly distorted square-planar coordination environment. The dihedral angles between the central benzene ring and the two outer rings are 7.62 (16) and 9.78 (17)°. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions with a centroid–centroid distance of 3.8218 (19) Å.
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spelling pubmed-29831942010-12-30 {6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Sahraei, Atefeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom has a slightly distorted square-planar coordination environment. The dihedral angles between the central benzene ring and the two outer rings are 7.62 (16) and 9.78 (17)°. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions with a centroid–centroid distance of 3.8218 (19) Å. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983194/ /pubmed/21587396 http://dx.doi.org/10.1107/S1600536810035890 Text en © Kargar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
Sahraei, Atefeh
{6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title {6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full {6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_fullStr {6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full_unstemmed {6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_short {6,6′-Dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_sort {6,6′-dimeth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983194/
https://www.ncbi.nlm.nih.gov/pubmed/21587396
http://dx.doi.org/10.1107/S1600536810035890
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AT tahirmuhammadnawaz 66dimethoxy2245dimethylophenylenebisnitrilomethylidynediphenolatonickelii
AT sahraeiatefeh 66dimethoxy2245dimethylophenylenebisnitrilomethylidynediphenolatonickelii

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