Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate

The title compound, [Co(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, is composed of one 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate anion lying on an inversion center, one [Co(H(2)O)(6)](2+) dicationic complex and a solvent water mol­ecule located on mirror planes. In the crystal, a chain is constructed v...

Descripción completa

Detalles Bibliográficos
Autores principales: Tang, Ping, Ma, Dan, Chen, Zhan-qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983201/
https://www.ncbi.nlm.nih.gov/pubmed/21587455
http://dx.doi.org/10.1107/S1600536810037451
_version_ 1782191824711974912
author Tang, Ping
Ma, Dan
Chen, Zhan-qing
author_facet Tang, Ping
Ma, Dan
Chen, Zhan-qing
author_sort Tang, Ping
collection PubMed
description The title compound, [Co(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, is composed of one 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate anion lying on an inversion center, one [Co(H(2)O)(6)](2+) dicationic complex and a solvent water mol­ecule located on mirror planes. In the crystal, a chain is constructed via O—H⋯O hydrogen bonds involving the carboxyl­ate and hydroxyl groups of the organic anion; the chains are further connected into a three-dimensional framework by additional O—H⋯O hydrogen bonds between the [Co(H(2)O)(6)](2+) cations, solvent water mol­ecules and the anions.
format Text
id pubmed-2983201
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29832012010-12-30 Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate Tang, Ping Ma, Dan Chen, Zhan-qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, is composed of one 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate anion lying on an inversion center, one [Co(H(2)O)(6)](2+) dicationic complex and a solvent water mol­ecule located on mirror planes. In the crystal, a chain is constructed via O—H⋯O hydrogen bonds involving the carboxyl­ate and hydroxyl groups of the organic anion; the chains are further connected into a three-dimensional framework by additional O—H⋯O hydrogen bonds between the [Co(H(2)O)(6)](2+) cations, solvent water mol­ecules and the anions. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983201/ /pubmed/21587455 http://dx.doi.org/10.1107/S1600536810037451 Text en © Tang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Ping
Ma, Dan
Chen, Zhan-qing
Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
title Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
title_full Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
title_fullStr Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
title_full_unstemmed Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
title_short Hexaaqua­cobalt(II) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
title_sort hexaaqua­cobalt(ii) 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983201/
https://www.ncbi.nlm.nih.gov/pubmed/21587455
http://dx.doi.org/10.1107/S1600536810037451
work_keys_str_mv AT tangping hexaaquacobaltii4412dihydroxyethane12diyldibenzoatemonohydrate
AT madan hexaaquacobaltii4412dihydroxyethane12diyldibenzoatemonohydrate
AT chenzhanqing hexaaquacobaltii4412dihydroxyethane12diyldibenzoatemonohydrate

Ejemplares similares