Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]

In the polymeric title compound, [Co(2)(C(3)H(7)NO)(3)(C(8)H(3)NO(6))(2)]·C(3)H(7)NO, one 5-nitro­isophthalate dianion has its two carboxyl­ate groups chelating to one Co(II) atom while simultaneously coordinating to another metal atom in a μ(4)-bridging mode. The other 5-nitro­isophthalte dianion h...

Descripción completa

Detalles Bibliográficos
Autores principales: Su, Meng, Huang, Zhan-Dong, Sun, Huang, Yang, Guang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983205/
https://www.ncbi.nlm.nih.gov/pubmed/21587377
http://dx.doi.org/10.1107/S1600536810035270
_version_ 1782191825673519104
author Su, Meng
Huang, Zhan-Dong
Sun, Huang
Yang, Guang
Ng, Seik Weng
author_facet Su, Meng
Huang, Zhan-Dong
Sun, Huang
Yang, Guang
Ng, Seik Weng
author_sort Su, Meng
collection PubMed
description In the polymeric title compound, [Co(2)(C(3)H(7)NO)(3)(C(8)H(3)NO(6))(2)]·C(3)H(7)NO, one 5-nitro­isophthalate dianion has its two carboxyl­ate groups chelating to one Co(II) atom while simultaneously coordinating to another metal atom in a μ(4)-bridging mode. The other 5-nitro­isophthalte dianion has one carboxyl­ate group chelating to a metal atom whereas the other bridges two metal atoms in a μ(3)-bridging mode. Both metal atoms show an octa­hedral coordination. The polymer adopts a layer motif, with the lattice dimethyl­formamide mol­ecules occupying the space between adjacent layers.
format Text
id pubmed-2983205
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29832052010-12-30 Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate] Su, Meng Huang, Zhan-Dong Sun, Huang Yang, Guang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [Co(2)(C(3)H(7)NO)(3)(C(8)H(3)NO(6))(2)]·C(3)H(7)NO, one 5-nitro­isophthalate dianion has its two carboxyl­ate groups chelating to one Co(II) atom while simultaneously coordinating to another metal atom in a μ(4)-bridging mode. The other 5-nitro­isophthalte dianion has one carboxyl­ate group chelating to a metal atom whereas the other bridges two metal atoms in a μ(3)-bridging mode. Both metal atoms show an octa­hedral coordination. The polymer adopts a layer motif, with the lattice dimethyl­formamide mol­ecules occupying the space between adjacent layers. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983205/ /pubmed/21587377 http://dx.doi.org/10.1107/S1600536810035270 Text en © Su et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Su, Meng
Huang, Zhan-Dong
Sun, Huang
Yang, Guang
Ng, Seik Weng
Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]
title Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]
title_full Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]
title_fullStr Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]
title_full_unstemmed Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]
title_short Poly[[tris­(N,N-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(II)] N,N-dimethyl­formamide monosolvate]
title_sort poly[[tris­(n,n-dimethyl­formamide)(μ(4)-5-nitro­isophthalato)(μ(3)-5-nitro­isophthalato)dicobalt(ii)] n,n-dimethyl­formamide monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983205/
https://www.ncbi.nlm.nih.gov/pubmed/21587377
http://dx.doi.org/10.1107/S1600536810035270
work_keys_str_mv AT sumeng polytrisnndimethylformamidem45nitroisophthalatom35nitroisophthalatodicobaltiinndimethylformamidemonosolvate
AT huangzhandong polytrisnndimethylformamidem45nitroisophthalatom35nitroisophthalatodicobaltiinndimethylformamidemonosolvate
AT sunhuang polytrisnndimethylformamidem45nitroisophthalatom35nitroisophthalatodicobaltiinndimethylformamidemonosolvate
AT yangguang polytrisnndimethylformamidem45nitroisophthalatom35nitroisophthalatodicobaltiinndimethylformamidemonosolvate
AT ngseikweng polytrisnndimethylformamidem45nitroisophthalatom35nitroisophthalatodicobaltiinndimethylformamidemonosolvate

Ejemplares similares