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(Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)

The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato (HL) ligands, three independent nitrate anions and one methanol mol­ecule coordinated to La(III). The coordination environment of th...

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Detalles Bibliográficos
Autores principales: Liu, Jia-Lu, Cai, Hai-Ting, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983206/
https://www.ncbi.nlm.nih.gov/pubmed/21587463
http://dx.doi.org/10.1107/S1600536810038109
Descripción
Sumario:The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato (HL) ligands, three independent nitrate anions and one methanol mol­ecule coordinated to La(III). The coordination environment of the La(III) ion is formed by eleven O atoms. Three bidentate nitrate anions coordinate to the La(III) ion, while two HL ligands chelate the metal center with O atoms from the phenolate and meth­oxy groups. The HL ligands are zwitterionic, with protonated imine N atoms. The coordination sphere is completed by one methanol mol­ecule. The protonated imine N atoms are involved in intra­molecular N—H⋯O hydrogen bonds with the phen­oxy groups and nitrate ligands. One O atom of one nitrate group is disordered over two sites of equal occupancy.