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(Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)

The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato (HL) ligands, three independent nitrate anions and one methanol mol­ecule coordinated to La(III). The coordination environment of th...

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Detalles Bibliográficos
Autores principales: Liu, Jia-Lu, Cai, Hai-Ting, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983206/
https://www.ncbi.nlm.nih.gov/pubmed/21587463
http://dx.doi.org/10.1107/S1600536810038109
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author Liu, Jia-Lu
Cai, Hai-Ting
Zhao, Guo-Liang
author_facet Liu, Jia-Lu
Cai, Hai-Ting
Zhao, Guo-Liang
author_sort Liu, Jia-Lu
collection PubMed
description The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato (HL) ligands, three independent nitrate anions and one methanol mol­ecule coordinated to La(III). The coordination environment of the La(III) ion is formed by eleven O atoms. Three bidentate nitrate anions coordinate to the La(III) ion, while two HL ligands chelate the metal center with O atoms from the phenolate and meth­oxy groups. The HL ligands are zwitterionic, with protonated imine N atoms. The coordination sphere is completed by one methanol mol­ecule. The protonated imine N atoms are involved in intra­molecular N—H⋯O hydrogen bonds with the phen­oxy groups and nitrate ligands. One O atom of one nitrate group is disordered over two sites of equal occupancy.
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spelling pubmed-29832062010-12-30 (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III) Liu, Jia-Lu Cai, Hai-Ting Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato (HL) ligands, three independent nitrate anions and one methanol mol­ecule coordinated to La(III). The coordination environment of the La(III) ion is formed by eleven O atoms. Three bidentate nitrate anions coordinate to the La(III) ion, while two HL ligands chelate the metal center with O atoms from the phenolate and meth­oxy groups. The HL ligands are zwitterionic, with protonated imine N atoms. The coordination sphere is completed by one methanol mol­ecule. The protonated imine N atoms are involved in intra­molecular N—H⋯O hydrogen bonds with the phen­oxy groups and nitrate ligands. One O atom of one nitrate group is disordered over two sites of equal occupancy. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983206/ /pubmed/21587463 http://dx.doi.org/10.1107/S1600536810038109 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jia-Lu
Cai, Hai-Ting
Zhao, Guo-Liang
(Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)
title (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)
title_full (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)
title_fullStr (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)
title_full_unstemmed (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)
title_short (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)lanthanum(III)
title_sort (methanol-κo)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) o,o′}tris­(nitrato-κ(2) o,o′)lanthanum(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983206/
https://www.ncbi.nlm.nih.gov/pubmed/21587463
http://dx.doi.org/10.1107/S1600536810038109
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