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(Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(nitrato-κ(2) O,O′)lanthanum(III)
The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato (HL) ligands, three independent nitrate anions and one methanol molecule coordinated to La(III). The coordination environment of th...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983206/ https://www.ncbi.nlm.nih.gov/pubmed/21587463 http://dx.doi.org/10.1107/S1600536810038109 |
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author | Liu, Jia-Lu Cai, Hai-Ting Zhao, Guo-Liang |
author_facet | Liu, Jia-Lu Cai, Hai-Ting Zhao, Guo-Liang |
author_sort | Liu, Jia-Lu |
collection | PubMed |
description | The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato (HL) ligands, three independent nitrate anions and one methanol molecule coordinated to La(III). The coordination environment of the La(III) ion is formed by eleven O atoms. Three bidentate nitrate anions coordinate to the La(III) ion, while two HL ligands chelate the metal center with O atoms from the phenolate and methoxy groups. The HL ligands are zwitterionic, with protonated imine N atoms. The coordination sphere is completed by one methanol molecule. The protonated imine N atoms are involved in intramolecular N—H⋯O hydrogen bonds with the phenoxy groups and nitrate ligands. One O atom of one nitrate group is disordered over two sites of equal occupancy. |
format | Text |
id | pubmed-2983206 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29832062010-12-30 (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(nitrato-κ(2) O,O′)lanthanum(III) Liu, Jia-Lu Cai, Hai-Ting Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [La(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato (HL) ligands, three independent nitrate anions and one methanol molecule coordinated to La(III). The coordination environment of the La(III) ion is formed by eleven O atoms. Three bidentate nitrate anions coordinate to the La(III) ion, while two HL ligands chelate the metal center with O atoms from the phenolate and methoxy groups. The HL ligands are zwitterionic, with protonated imine N atoms. The coordination sphere is completed by one methanol molecule. The protonated imine N atoms are involved in intramolecular N—H⋯O hydrogen bonds with the phenoxy groups and nitrate ligands. One O atom of one nitrate group is disordered over two sites of equal occupancy. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983206/ /pubmed/21587463 http://dx.doi.org/10.1107/S1600536810038109 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jia-Lu Cai, Hai-Ting Zhao, Guo-Liang (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(nitrato-κ(2) O,O′)lanthanum(III) |
title | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)lanthanum(III) |
title_full | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)lanthanum(III) |
title_fullStr | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)lanthanum(III) |
title_full_unstemmed | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)lanthanum(III) |
title_short | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)lanthanum(III) |
title_sort | (methanol-κo)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
o,o′}tris(nitrato-κ(2)
o,o′)lanthanum(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983206/ https://www.ncbi.nlm.nih.gov/pubmed/21587463 http://dx.doi.org/10.1107/S1600536810038109 |
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