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Tetra­aqua­bis­(μ(2)-4,4′-bipyridine)­dodeca­kis­(μ(2)-2-methyl­prop-2-enoato)octa­kis­(2-methyl­prop-2-enoato)tetra­ytterbium(III)tetra­zinc(II)

The asymmetric unit of the title compound, [Yb(4)Zn(4)(C(4)H(5)O(2))(20)(C(10)H(8)N(2))(2)(H(2)O)(4)], contains half of a centrosymmetric octa­nuclear mol­ecule in which each Zn(II) ion is four-coordinated by three O atoms from three 2-methyl­prop-2-enoate (L) ligands and one N atom from a 4,4′-bipy...

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Detalles Bibliográficos
Autores principales: Wu, Bin, Zhao, Chengxin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983210/
https://www.ncbi.nlm.nih.gov/pubmed/21587363
http://dx.doi.org/10.1107/S1600536810034215
Descripción
Sumario:The asymmetric unit of the title compound, [Yb(4)Zn(4)(C(4)H(5)O(2))(20)(C(10)H(8)N(2))(2)(H(2)O)(4)], contains half of a centrosymmetric octa­nuclear mol­ecule in which each Zn(II) ion is four-coordinated by three O atoms from three 2-methyl­prop-2-enoate (L) ligands and one N atom from a 4,4′-bipyridine (bipy) ligand in a distorted pyramidal geometry. The two independent Yb(III) ions, each coordinated by eight O atoms in an irregular geometry, exhibit different coordination environments, viz. one water mol­ecule, five bridging bidentate and one chelating bidentate carboxyl­ate groups for one Yb(III) ion, and one water mol­ecule, three bridging bidentate and two chelating bidentate carboxyl­ate groups for the other Yb(III) ion. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds help to establish the packing.