[μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]

The title dinuclear cadmium complex, [Cd(2)(NO(3))(4)(C(28)H(32)N(6))], is located on an inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl­amine group of the ligand via the N atoms in a meridional fashion and two O...

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Detalles Bibliográficos
Autores principales: Bartholomä, Mark, Cheung, Hoi, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983215/
https://www.ncbi.nlm.nih.gov/pubmed/21587358
http://dx.doi.org/10.1107/S1600536810034549
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author Bartholomä, Mark
Cheung, Hoi
Zubieta, Jon
author_facet Bartholomä, Mark
Cheung, Hoi
Zubieta, Jon
author_sort Bartholomä, Mark
collection PubMed
description The title dinuclear cadmium complex, [Cd(2)(NO(3))(4)(C(28)H(32)N(6))], is located on an inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl­amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands.
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spelling pubmed-29832152010-12-30 [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)] Bartholomä, Mark Cheung, Hoi Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear cadmium complex, [Cd(2)(NO(3))(4)(C(28)H(32)N(6))], is located on an inversion center. The unique Cd(II) ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl­amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983215/ /pubmed/21587358 http://dx.doi.org/10.1107/S1600536810034549 Text en © Bartholomä et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bartholomä, Mark
Cheung, Hoi
Zubieta, Jon
[μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]
title [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]
title_full [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]
title_fullStr [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]
title_full_unstemmed [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]
title_short [μ-N,N,N′,N′-Tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(II)]
title_sort [μ-n,n,n′,n′-tetra­kis(2-pyridyl­meth­yl)butane-1,4-diamine]­bis­[dinitratocadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983215/
https://www.ncbi.nlm.nih.gov/pubmed/21587358
http://dx.doi.org/10.1107/S1600536810034549
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AT zubietajon mnnnntetrakis2pyridylmethylbutane14diaminebisdinitratocadmiumii

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