Cargando…
catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2) O (1):O (3)]]
The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxylate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generat...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983217/ https://www.ncbi.nlm.nih.gov/pubmed/21587413 http://dx.doi.org/10.1107/S1600536810036500 |
| _version_ | 1782191828597997568 |
|---|---|
| author | Shams-ul-Islam, S. Bhatti, Moazzam H. Imtiaz-ud-Din, Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Shams-ul-Islam, S. Bhatti, Moazzam H. Imtiaz-ud-Din, Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Shams-ul-Islam, S. |
| collection | PubMed |
| description | The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxylate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intramolecular carboxylate–carbonyl N—H⋯O hydrogen bond is responsible for the curved conformation within the carboxylate ligand. |
| format | Text |
| id | pubmed-2983217 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29832172010-12-30 catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2) O (1):O (3)]] Shams-ul-Islam, S. Bhatti, Moazzam H. Imtiaz-ud-Din, Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxylate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intramolecular carboxylate–carbonyl N—H⋯O hydrogen bond is responsible for the curved conformation within the carboxylate ligand. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983217/ /pubmed/21587413 http://dx.doi.org/10.1107/S1600536810036500 Text en © Shams-ul-Islam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shams-ul-Islam, S. Bhatti, Moazzam H. Imtiaz-ud-Din, Ng, Seik Weng Tiekink, Edward R. T. catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2) O (1):O (3)]] |
| title |
catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2)
O
(1):O
(3)]] |
| title_full |
catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2)
O
(1):O
(3)]] |
| title_fullStr |
catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2)
O
(1):O
(3)]] |
| title_full_unstemmed |
catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2)
O
(1):O
(3)]] |
| title_short |
catena-Poly[[triphenyltin(IV)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2)
O
(1):O
(3)]] |
| title_sort | catena-poly[[triphenyltin(iv)]-μ(2)-[3-(cyclohexylcarbamoyl)propanoato-κ(2)
o
(1):o
(3)]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983217/ https://www.ncbi.nlm.nih.gov/pubmed/21587413 http://dx.doi.org/10.1107/S1600536810036500 |
| work_keys_str_mv | AT shamsulislams catenapolytriphenyltinivm23cyclohexylcarbamoylpropanoatok2o1o3 AT bhattimoazzamh catenapolytriphenyltinivm23cyclohexylcarbamoylpropanoatok2o1o3 AT imtiazuddin catenapolytriphenyltinivm23cyclohexylcarbamoylpropanoatok2o1o3 AT ngseikweng catenapolytriphenyltinivm23cyclohexylcarbamoylpropanoatok2o1o3 AT tiekinkedwardrt catenapolytriphenyltinivm23cyclohexylcarbamoylpropanoatok2o1o3 |