1-(2,5-Dichloro-3-thien­yl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds

In the title compound, C(6)H(4)Cl(2)OS, the acetyl group is almost coplanar with the thio­phene ring [dihedral angle = 4.01 (2)°]. In the crystal, short inter­molecular O⋯Cl contacts [2.9494 (14) and 3.1191 (14) Å] link the mol­ecules into infinite (100) sheets and aromatic π–π stacking [centroid–ce...

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Detalles Bibliográficos
Autores principales: Harrison, William T. A., Chidan Kumar, C. S., Yathirajan, H. S., Mayekar, A. N., Narayana, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983218/
https://www.ncbi.nlm.nih.gov/pubmed/21587481
http://dx.doi.org/10.1107/S1600536810035154
Descripción
Sumario:In the title compound, C(6)H(4)Cl(2)OS, the acetyl group is almost coplanar with the thio­phene ring [dihedral angle = 4.01 (2)°]. In the crystal, short inter­molecular O⋯Cl contacts [2.9494 (14) and 3.1191 (14) Å] link the mol­ecules into infinite (100) sheets and aromatic π–π stacking [centroid–centroid separation = 3.5422 (10) Å] consolidates the packing.

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