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1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds
In the title compound, C(6)H(4)Cl(2)OS, the acetyl group is almost coplanar with the thiophene ring [dihedral angle = 4.01 (2)°]. In the crystal, short intermolecular O⋯Cl contacts [2.9494 (14) and 3.1191 (14) Å] link the molecules into infinite (100) sheets and aromatic π–π stacking [centroid–ce...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983218/ https://www.ncbi.nlm.nih.gov/pubmed/21587481 http://dx.doi.org/10.1107/S1600536810035154 |
| _version_ | 1782191828839170048 |
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| author | Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. |
| author_facet | Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. |
| author_sort | Harrison, William T. A. |
| collection | PubMed |
| description | In the title compound, C(6)H(4)Cl(2)OS, the acetyl group is almost coplanar with the thiophene ring [dihedral angle = 4.01 (2)°]. In the crystal, short intermolecular O⋯Cl contacts [2.9494 (14) and 3.1191 (14) Å] link the molecules into infinite (100) sheets and aromatic π–π stacking [centroid–centroid separation = 3.5422 (10) Å] consolidates the packing. |
| format | Text |
| id | pubmed-2983218 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29832182010-12-30 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(4)Cl(2)OS, the acetyl group is almost coplanar with the thiophene ring [dihedral angle = 4.01 (2)°]. In the crystal, short intermolecular O⋯Cl contacts [2.9494 (14) and 3.1191 (14) Å] link the molecules into infinite (100) sheets and aromatic π–π stacking [centroid–centroid separation = 3.5422 (10) Å] consolidates the packing. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983218/ /pubmed/21587481 http://dx.doi.org/10.1107/S1600536810035154 Text en © Harrison et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds |
| title | 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds |
| title_full | 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds |
| title_fullStr | 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds |
| title_full_unstemmed | 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds |
| title_short | 1-(2,5-Dichloro-3-thienyl)ethanone: infinite sheets mediated by O⋯Cl halogen bonds |
| title_sort | 1-(2,5-dichloro-3-thienyl)ethanone: infinite sheets mediated by o⋯cl halogen bonds |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983218/ https://www.ncbi.nlm.nih.gov/pubmed/21587481 http://dx.doi.org/10.1107/S1600536810035154 |
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