Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II) mono­hydrate

In the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·H(2)O, the Mn(II) cation, located on a twofold rotation axis, is N,O-chelated by two 3-amino­pyrazine-2-carboxyl­ate anions and coordin­ated by two water mol­ecules in a distorted octa­hedral geometry. The uncoordinated water mol­ecules lies...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983226/
https://www.ncbi.nlm.nih.gov/pubmed/21587379
http://dx.doi.org/10.1107/S1600536810035233
Descripción
Sumario:In the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·H(2)O, the Mn(II) cation, located on a twofold rotation axis, is N,O-chelated by two 3-amino­pyrazine-2-carboxyl­ate anions and coordin­ated by two water mol­ecules in a distorted octa­hedral geometry. The uncoordinated water mol­ecules lies on a twofold rotation axis. Adjacent mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network motif.

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