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Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquamanganese(II) monohydrate
In the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·H(2)O, the Mn(II) cation, located on a twofold rotation axis, is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and coordinated by two water molecules in a distorted octahedral geometry. The uncoordinated water molecules lies...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983226/ https://www.ncbi.nlm.nih.gov/pubmed/21587379 http://dx.doi.org/10.1107/S1600536810035233 |
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author | Gao, Shan Ng, Seik Weng |
author_facet | Gao, Shan Ng, Seik Weng |
author_sort | Gao, Shan |
collection | PubMed |
description | In the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·H(2)O, the Mn(II) cation, located on a twofold rotation axis, is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and coordinated by two water molecules in a distorted octahedral geometry. The uncoordinated water molecules lies on a twofold rotation axis. Adjacent molecules are linked by O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network motif. |
format | Text |
id | pubmed-2983226 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29832262010-12-30 Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquamanganese(II) monohydrate Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·H(2)O, the Mn(II) cation, located on a twofold rotation axis, is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and coordinated by two water molecules in a distorted octahedral geometry. The uncoordinated water molecules lies on a twofold rotation axis. Adjacent molecules are linked by O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network motif. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983226/ /pubmed/21587379 http://dx.doi.org/10.1107/S1600536810035233 Text en © Gao and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Shan Ng, Seik Weng Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquamanganese(II) monohydrate |
title | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquamanganese(II) monohydrate |
title_full | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquamanganese(II) monohydrate |
title_fullStr | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquamanganese(II) monohydrate |
title_full_unstemmed | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquamanganese(II) monohydrate |
title_short | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquamanganese(II) monohydrate |
title_sort | bis(3-aminopyrazine-2-carboxylato-κ(2)
n
(1),o)diaquamanganese(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983226/ https://www.ncbi.nlm.nih.gov/pubmed/21587379 http://dx.doi.org/10.1107/S1600536810035233 |
work_keys_str_mv | AT gaoshan bis3aminopyrazine2carboxylatok2n1odiaquamanganeseiimonohydrate AT ngseikweng bis3aminopyrazine2carboxylatok2n1odiaquamanganeseiimonohydrate |