Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate

In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa­hedral geometry. A supra­molecular network is formed via inter­molecular O—H⋯O and C...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Xiao-Jun, Zheng, Chun, Mai, Shao-Wei, Xu, Xuan, Luo, Yi-Fan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983227/
https://www.ncbi.nlm.nih.gov/pubmed/21587395
http://dx.doi.org/10.1107/S1600536810035555
_version_ 1782191830993993728
author Wang, Xiao-Jun
Zheng, Chun
Mai, Shao-Wei
Xu, Xuan
Luo, Yi-Fan
author_facet Wang, Xiao-Jun
Zheng, Chun
Mai, Shao-Wei
Xu, Xuan
Luo, Yi-Fan
author_sort Wang, Xiao-Jun
collection PubMed
description In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa­hedral geometry. A supra­molecular network is formed via inter­molecular O—H⋯O and C—H⋯O hydrogen-bonding inter­actions. π–π stacking inter­actions between neighboring pyridine rings are also present, the centroid—centroid distance being 3.808 (2) Å.
format Text
id pubmed-2983227
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29832272010-12-30 Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate Wang, Xiao-Jun Zheng, Chun Mai, Shao-Wei Xu, Xuan Luo, Yi-Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa­hedral geometry. A supra­molecular network is formed via inter­molecular O—H⋯O and C—H⋯O hydrogen-bonding inter­actions. π–π stacking inter­actions between neighboring pyridine rings are also present, the centroid—centroid distance being 3.808 (2) Å. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983227/ /pubmed/21587395 http://dx.doi.org/10.1107/S1600536810035555 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xiao-Jun
Zheng, Chun
Mai, Shao-Wei
Xu, Xuan
Luo, Yi-Fan
Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate
title Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate
title_full Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate
title_fullStr Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate
title_full_unstemmed Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate
title_short Bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(II) nitrate dihydrate
title_sort bis(2,2′-bipyridine)(2-hy­droxy-2,2-diphenyl­acetato)­copper(ii) nitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983227/
https://www.ncbi.nlm.nih.gov/pubmed/21587395
http://dx.doi.org/10.1107/S1600536810035555
work_keys_str_mv AT wangxiaojun bis22bipyridine2hydroxy22diphenylacetatocopperiinitratedihydrate
AT zhengchun bis22bipyridine2hydroxy22diphenylacetatocopperiinitratedihydrate
AT maishaowei bis22bipyridine2hydroxy22diphenylacetatocopperiinitratedihydrate
AT xuxuan bis22bipyridine2hydroxy22diphenylacetatocopperiinitratedihydrate
AT luoyifan bis22bipyridine2hydroxy22diphenylacetatocopperiinitratedihydrate

Ejemplares similares