[(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)

In the title complex, [Mn(NCS)(2)(C(6)H(7)NO)(2)], the Mn(II) atom shows site symmetry 2. The distorted octa­hedral environment of Mn(II) is defined by two N atoms [Mn—N = 2.217 (4) and 2.132 (5) Å] and one O atom [Mn—O 2.305 (4) Å]. There are inter­molecular O—H⋯S hydrogen bonds and inter­molecular...

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Detalles Bibliográficos
Autores principales: Gao, Qihe, Bao, Qianqian, Rong, Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983231/
https://www.ncbi.nlm.nih.gov/pubmed/21587362
http://dx.doi.org/10.1107/S1600536810034483
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author Gao, Qihe
Bao, Qianqian
Rong, Rong
author_facet Gao, Qihe
Bao, Qianqian
Rong, Rong
author_sort Gao, Qihe
collection PubMed
description In the title complex, [Mn(NCS)(2)(C(6)H(7)NO)(2)], the Mn(II) atom shows site symmetry 2. The distorted octa­hedral environment of Mn(II) is defined by two N atoms [Mn—N = 2.217 (4) and 2.132 (5) Å] and one O atom [Mn—O 2.305 (4) Å]. There are inter­molecular O—H⋯S hydrogen bonds and inter­molecular π–π stacking inter­actions between adjacent (2-pyrid­yl)methano­late ligands [centroid–centroid distance = 3.5569 (7) Å], leading to a chain structure running along [100].
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spelling pubmed-29832312010-12-30 [(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II) Gao, Qihe Bao, Qianqian Rong, Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(NCS)(2)(C(6)H(7)NO)(2)], the Mn(II) atom shows site symmetry 2. The distorted octa­hedral environment of Mn(II) is defined by two N atoms [Mn—N = 2.217 (4) and 2.132 (5) Å] and one O atom [Mn—O 2.305 (4) Å]. There are inter­molecular O—H⋯S hydrogen bonds and inter­molecular π–π stacking inter­actions between adjacent (2-pyrid­yl)methano­late ligands [centroid–centroid distance = 3.5569 (7) Å], leading to a chain structure running along [100]. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983231/ /pubmed/21587362 http://dx.doi.org/10.1107/S1600536810034483 Text en © Gao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Qihe
Bao, Qianqian
Rong, Rong
[(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)
title [(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)
title_full [(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)
title_fullStr [(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)
title_full_unstemmed [(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)
title_short [(2-Pyrid­yl)methanol-κ(2) N,O]bis­(thio­cyanato-κN)manganese(II)
title_sort [(2-pyrid­yl)methanol-κ(2) n,o]bis­(thio­cyanato-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983231/
https://www.ncbi.nlm.nih.gov/pubmed/21587362
http://dx.doi.org/10.1107/S1600536810034483
work_keys_str_mv AT gaoqihe 2pyridylmethanolk2nobisthiocyanatoknmanganeseii
AT baoqianqian 2pyridylmethanolk2nobisthiocyanatoknmanganeseii
AT rongrong 2pyridylmethanolk2nobisthiocyanatoknmanganeseii

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