N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide

The title acetamide compound, C(8)H(9)BrN(2)O, crystallizes with three crystallographically independent mol­ecules (A, B and C) in the asymmetric unit. In mol­ecule A, the mean plane through the acetamide unit is inclined at a dihedral angle of 4.40 (11)° with respect to the pyridine ring [10.31 (12...

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Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Das, Nirmal Kumar, Sen, Debabrata, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983235/
https://www.ncbi.nlm.nih.gov/pubmed/21587497
http://dx.doi.org/10.1107/S1600536810035026
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author Fun, Hoong-Kun
Goh, Jia Hao
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description The title acetamide compound, C(8)H(9)BrN(2)O, crystallizes with three crystallographically independent mol­ecules (A, B and C) in the asymmetric unit. In mol­ecule A, the mean plane through the acetamide unit is inclined at a dihedral angle of 4.40 (11)° with respect to the pyridine ring [10.31 (12) and 2.27 (11)°, respectively, for mol­ecules B and C]. In the crystal structure, mol­ecules are inter­connected into sheets parallel to the ac plane by N—H⋯O, C—H⋯Br, C—H⋯O and C—H⋯N hydrogen bonds. The structure is further stabilized by weak inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29832352010-12-30 N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide Fun, Hoong-Kun Goh, Jia Hao Das, Nirmal Kumar Sen, Debabrata Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title acetamide compound, C(8)H(9)BrN(2)O, crystallizes with three crystallographically independent mol­ecules (A, B and C) in the asymmetric unit. In mol­ecule A, the mean plane through the acetamide unit is inclined at a dihedral angle of 4.40 (11)° with respect to the pyridine ring [10.31 (12) and 2.27 (11)°, respectively, for mol­ecules B and C]. In the crystal structure, mol­ecules are inter­connected into sheets parallel to the ac plane by N—H⋯O, C—H⋯Br, C—H⋯O and C—H⋯N hydrogen bonds. The structure is further stabilized by weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983235/ /pubmed/21587497 http://dx.doi.org/10.1107/S1600536810035026 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide
title N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide
title_full N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide
title_fullStr N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide
title_full_unstemmed N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide
title_short N-(6-Bromo­meth­yl-2-pyrid­yl)acetamide
title_sort n-(6-bromo­meth­yl-2-pyrid­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983235/
https://www.ncbi.nlm.nih.gov/pubmed/21587497
http://dx.doi.org/10.1107/S1600536810035026
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AT gohjiahao n6bromomethyl2pyridylacetamide
AT dasnirmalkumar n6bromomethyl2pyridylacetamide
AT sendebabrata n6bromomethyl2pyridylacetamide
AT goswamishyamaprosad n6bromomethyl2pyridylacetamide

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