Cargando…
A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2) N (1):N (1′)]bis[dinitritozinc(II)]
The coordination geometry of the Zn(II) atom in the title complex, [Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)], is distorted octahedral, in which the Zn(II) atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two...
| Autores principales: | , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983239/ https://www.ncbi.nlm.nih.gov/pubmed/21587367 http://dx.doi.org/10.1107/S1600536810034203 |
| _version_ | 1782191833853460480 |
|---|---|
| author | Zhang, Rongxian Chen, Qiuyun Gao, Jing Wu, Xiangyang |
| author_facet | Zhang, Rongxian Chen, Qiuyun Gao, Jing Wu, Xiangyang |
| author_sort | Zhang, Rongxian |
| collection | PubMed |
| description | The coordination geometry of the Zn(II) atom in the title complex, [Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)], is distorted octahedral, in which the Zn(II) atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two nitrite ligands. Two Zn(II) atoms are bridged by two organic ligands, forming a centrosymmetric dimer. Weak C—H⋯N and C—H⋯O hydrogen bonds play an important role in the intermolecular packing. |
| format | Text |
| id | pubmed-2983239 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29832392010-12-30 A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2) N (1):N (1′)]bis[dinitritozinc(II)] Zhang, Rongxian Chen, Qiuyun Gao, Jing Wu, Xiangyang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination geometry of the Zn(II) atom in the title complex, [Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)], is distorted octahedral, in which the Zn(II) atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two nitrite ligands. Two Zn(II) atoms are bridged by two organic ligands, forming a centrosymmetric dimer. Weak C—H⋯N and C—H⋯O hydrogen bonds play an important role in the intermolecular packing. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983239/ /pubmed/21587367 http://dx.doi.org/10.1107/S1600536810034203 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Rongxian Chen, Qiuyun Gao, Jing Wu, Xiangyang A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2) N (1):N (1′)]bis[dinitritozinc(II)] |
| title | A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2)
N
(1):N
(1′)]bis[dinitritozinc(II)] |
| title_full | A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2)
N
(1):N
(1′)]bis[dinitritozinc(II)] |
| title_fullStr | A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2)
N
(1):N
(1′)]bis[dinitritozinc(II)] |
| title_full_unstemmed | A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2)
N
(1):N
(1′)]bis[dinitritozinc(II)] |
| title_short | A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2)
N
(1):N
(1′)]bis[dinitritozinc(II)] |
| title_sort | dimeric zinc(ii) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ(2)
n
(1):n
(1′)]bis[dinitritozinc(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983239/ https://www.ncbi.nlm.nih.gov/pubmed/21587367 http://dx.doi.org/10.1107/S1600536810034203 |
| work_keys_str_mv | AT zhangrongxian adimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT chenqiuyun adimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT gaojing adimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT wuxiangyang adimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT zhangrongxian dimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT chenqiuyun dimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT gaojing dimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii AT wuxiangyang dimericzinciicomplexbism12bis124triazol4ylethanek2n1n1bisdinitritozincii |