2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)

The asymmetric unit of the title co-crystal solvate, C(14)H(10)O(4)S(2)·2C(14)H(12)N(2)·C(4)H(8)O, comprises a 2,2′-(disulfanedi­yl)dibenzoic acid mol­ecule, two mol­ecules of 2,9-dimethyl­phenanthroline and a tetra­hydro­furan (THF) solvent mol­ecule. Each end of the twisted diacid [dihedral angle...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Kaulgud, Trupta, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983249/
https://www.ncbi.nlm.nih.gov/pubmed/21587579
http://dx.doi.org/10.1107/S1600536810037165
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author Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The asymmetric unit of the title co-crystal solvate, C(14)H(10)O(4)S(2)·2C(14)H(12)N(2)·C(4)H(8)O, comprises a 2,2′-(disulfanedi­yl)dibenzoic acid mol­ecule, two mol­ecules of 2,9-dimethyl­phenanthroline and a tetra­hydro­furan (THF) solvent mol­ecule. Each end of the twisted diacid [dihedral angle between the benzene rings = 74.33 (17)°] forms a strong O—H⋯N hydrogen bond with a 2,9-dimethyl­phenanthroline mol­ecule, forming a trimeric aggregate. The crystal structure comprises layers of acid and THF mol­ecules, and layers of 2,9-dimethyl­phenanthroline mol­ecules that alternate along the a axis, the main connections between them being of the type C—H⋯O.
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spelling pubmed-29832492010-12-30 2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title co-crystal solvate, C(14)H(10)O(4)S(2)·2C(14)H(12)N(2)·C(4)H(8)O, comprises a 2,2′-(disulfanedi­yl)dibenzoic acid mol­ecule, two mol­ecules of 2,9-dimethyl­phenanthroline and a tetra­hydro­furan (THF) solvent mol­ecule. Each end of the twisted diacid [dihedral angle between the benzene rings = 74.33 (17)°] forms a strong O—H⋯N hydrogen bond with a 2,9-dimethyl­phenanthroline mol­ecule, forming a trimeric aggregate. The crystal structure comprises layers of acid and THF mol­ecules, and layers of 2,9-dimethyl­phenanthroline mol­ecules that alternate along the a axis, the main connections between them being of the type C—H⋯O. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983249/ /pubmed/21587579 http://dx.doi.org/10.1107/S1600536810037165 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
title 2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
title_full 2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
title_fullStr 2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
title_full_unstemmed 2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
title_short 2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
title_sort 2,2′-(disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983249/
https://www.ncbi.nlm.nih.gov/pubmed/21587579
http://dx.doi.org/10.1107/S1600536810037165
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AT kaulgudtrupta 22disulfanediyldibenzoicacid29dimethylphenanthrolinetetrahydrofuran121
AT tiekinkedwardrt 22disulfanediyldibenzoicacid29dimethylphenanthrolinetetrahydrofuran121

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