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Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)

In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenyl­phosphan­yl)meth­yl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A...

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Detalles Bibliográficos
Autores principales: Wang, Zi-Jia, Wang, Xiao-Xi, Wan, Chong-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983250/
https://www.ncbi.nlm.nih.gov/pubmed/21587470
http://dx.doi.org/10.1107/S1600536810038134
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author Wang, Zi-Jia
Wang, Xiao-Xi
Wan, Chong-Qing
author_facet Wang, Zi-Jia
Wang, Xiao-Xi
Wan, Chong-Qing
author_sort Wang, Zi-Jia
collection PubMed
description In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenyl­phosphan­yl)meth­yl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt(II) atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C—H⋯π inter­actions, which link the mol­ecules into chains along the c axis.
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spelling pubmed-29832502010-12-30 Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II) Wang, Zi-Jia Wang, Xiao-Xi Wan, Chong-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenyl­phosphan­yl)meth­yl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt(II) atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C—H⋯π inter­actions, which link the mol­ecules into chains along the c axis. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983250/ /pubmed/21587470 http://dx.doi.org/10.1107/S1600536810038134 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zi-Jia
Wang, Xiao-Xi
Wan, Chong-Qing
Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)
title Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)
title_full Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)
title_fullStr Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)
title_full_unstemmed Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)
title_short Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(II)
title_sort chlorido{n (2),n (6)-dibenzyl-n (2),n (6)-bis­[(diphenyl­phosphan­yl)meth­yl]pyridine-2,6-diamine}­methyl­platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983250/
https://www.ncbi.nlm.nih.gov/pubmed/21587470
http://dx.doi.org/10.1107/S1600536810038134
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