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Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II)
In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenylphosphanyl)methyl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983250/ https://www.ncbi.nlm.nih.gov/pubmed/21587470 http://dx.doi.org/10.1107/S1600536810038134 |
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author | Wang, Zi-Jia Wang, Xiao-Xi Wan, Chong-Qing |
author_facet | Wang, Zi-Jia Wang, Xiao-Xi Wan, Chong-Qing |
author_sort | Wang, Zi-Jia |
collection | PubMed |
description | In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenylphosphanyl)methyl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt(II) atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C—H⋯π interactions, which link the molecules into chains along the c axis. |
format | Text |
id | pubmed-2983250 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29832502010-12-30 Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) Wang, Zi-Jia Wang, Xiao-Xi Wan, Chong-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenylphosphanyl)methyl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt(II) atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C—H⋯π interactions, which link the molecules into chains along the c axis. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983250/ /pubmed/21587470 http://dx.doi.org/10.1107/S1600536810038134 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Zi-Jia Wang, Xiao-Xi Wan, Chong-Qing Chlorido{N (2),N (6)-dibenzyl-N (2),N (6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) |
title | Chlorido{N
(2),N
(6)-dibenzyl-N
(2),N
(6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) |
title_full | Chlorido{N
(2),N
(6)-dibenzyl-N
(2),N
(6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) |
title_fullStr | Chlorido{N
(2),N
(6)-dibenzyl-N
(2),N
(6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) |
title_full_unstemmed | Chlorido{N
(2),N
(6)-dibenzyl-N
(2),N
(6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) |
title_short | Chlorido{N
(2),N
(6)-dibenzyl-N
(2),N
(6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(II) |
title_sort | chlorido{n
(2),n
(6)-dibenzyl-n
(2),n
(6)-bis[(diphenylphosphanyl)methyl]pyridine-2,6-diamine}methylplatinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983250/ https://www.ncbi.nlm.nih.gov/pubmed/21587470 http://dx.doi.org/10.1107/S1600536810038134 |
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