μ-Actetato-1:2κ(2) O:O′-tribromido-2κ(3) Br-(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene-1κ(4) N)dizinc(II)

In the title compound, [Zn(2)Br(3)(CH(3)COO)(C(16)H(32)N(4))], one Zn(II) atom has a distorted square-planar coordination formed by the four macrocyclic N atoms with an acetate O atom in the apical position and the other Zn(II) atom has a tetra­hedral coordination environment formed by three Br atom...

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Detalles Bibliográficos
Autores principales: Li, HuaFeng, Shi, FeiFei, Rong, Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983256/
https://www.ncbi.nlm.nih.gov/pubmed/21587467
http://dx.doi.org/10.1107/S1600536810033702
Descripción
Sumario:In the title compound, [Zn(2)Br(3)(CH(3)COO)(C(16)H(32)N(4))], one Zn(II) atom has a distorted square-planar coordination formed by the four macrocyclic N atoms with an acetate O atom in the apical position and the other Zn(II) atom has a tetra­hedral coordination environment formed by three Br atoms and one O acetate atom. The two Zn(II) atoms are linked by an acetate bridge. In the crystal, mol­ecules are linked into centrosymmetric dimers with graph-set motifs R (2) (2)(16) by an N—H⋯Br inter­action. The mol­ecular configuration is stabilized by an intra­molecular N—H⋯Br hydrogen bond.

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