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μ-Actetato-1:2κ(2) O:O′-tribromido-2κ(3) Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4) N)dizinc(II)
In the title compound, [Zn(2)Br(3)(CH(3)COO)(C(16)H(32)N(4))], one Zn(II) atom has a distorted square-planar coordination formed by the four macrocyclic N atoms with an acetate O atom in the apical position and the other Zn(II) atom has a tetrahedral coordination environment formed by three Br atom...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983256/ https://www.ncbi.nlm.nih.gov/pubmed/21587467 http://dx.doi.org/10.1107/S1600536810033702 |
| _version_ | 1782191837946052608 |
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| author | Li, HuaFeng Shi, FeiFei Rong, Rong |
| author_facet | Li, HuaFeng Shi, FeiFei Rong, Rong |
| author_sort | Li, HuaFeng |
| collection | PubMed |
| description | In the title compound, [Zn(2)Br(3)(CH(3)COO)(C(16)H(32)N(4))], one Zn(II) atom has a distorted square-planar coordination formed by the four macrocyclic N atoms with an acetate O atom in the apical position and the other Zn(II) atom has a tetrahedral coordination environment formed by three Br atoms and one O acetate atom. The two Zn(II) atoms are linked by an acetate bridge. In the crystal, molecules are linked into centrosymmetric dimers with graph-set motifs R (2) (2)(16) by an N—H⋯Br interaction. The molecular configuration is stabilized by an intramolecular N—H⋯Br hydrogen bond. |
| format | Text |
| id | pubmed-2983256 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29832562010-12-30 μ-Actetato-1:2κ(2) O:O′-tribromido-2κ(3) Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4) N)dizinc(II) Li, HuaFeng Shi, FeiFei Rong, Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(2)Br(3)(CH(3)COO)(C(16)H(32)N(4))], one Zn(II) atom has a distorted square-planar coordination formed by the four macrocyclic N atoms with an acetate O atom in the apical position and the other Zn(II) atom has a tetrahedral coordination environment formed by three Br atoms and one O acetate atom. The two Zn(II) atoms are linked by an acetate bridge. In the crystal, molecules are linked into centrosymmetric dimers with graph-set motifs R (2) (2)(16) by an N—H⋯Br interaction. The molecular configuration is stabilized by an intramolecular N—H⋯Br hydrogen bond. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983256/ /pubmed/21587467 http://dx.doi.org/10.1107/S1600536810033702 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, HuaFeng Shi, FeiFei Rong, Rong μ-Actetato-1:2κ(2) O:O′-tribromido-2κ(3) Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4) N)dizinc(II) |
| title | μ-Actetato-1:2κ(2)
O:O′-tribromido-2κ(3)
Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4)
N)dizinc(II) |
| title_full | μ-Actetato-1:2κ(2)
O:O′-tribromido-2κ(3)
Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4)
N)dizinc(II) |
| title_fullStr | μ-Actetato-1:2κ(2)
O:O′-tribromido-2κ(3)
Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4)
N)dizinc(II) |
| title_full_unstemmed | μ-Actetato-1:2κ(2)
O:O′-tribromido-2κ(3)
Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4)
N)dizinc(II) |
| title_short | μ-Actetato-1:2κ(2)
O:O′-tribromido-2κ(3)
Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4)
N)dizinc(II) |
| title_sort | μ-actetato-1:2κ(2)
o:o′-tribromido-2κ(3)
br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ(4)
n)dizinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983256/ https://www.ncbi.nlm.nih.gov/pubmed/21587467 http://dx.doi.org/10.1107/S1600536810033702 |
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