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4-(3-Fluorophenyl)-1-(2-oxoindolin-3-ylidene)thiosemicarbazide
In the title compound, C(15)H(11)FN(4)OS, there are three independent molecules, each with a disordered 3-fluorophenyl group [occupancy ratios = 0.547 (17):0.453 (17), 0.645 (5):0.355 (5) and 0.626 (15):0.374 (15)] and displaying dihedral angles of 4.2 (3), 25.2 (6) and 32.4 (5)° between the 2-oxo...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983261/ https://www.ncbi.nlm.nih.gov/pubmed/21587492 http://dx.doi.org/10.1107/S1600536810034951 |
Sumario: | In the title compound, C(15)H(11)FN(4)OS, there are three independent molecules, each with a disordered 3-fluorophenyl group [occupancy ratios = 0.547 (17):0.453 (17), 0.645 (5):0.355 (5) and 0.626 (15):0.374 (15)] and displaying dihedral angles of 4.2 (3), 25.2 (6) and 32.4 (5)° between the 2-oxoindoline and fluoro-substituted phenyl rings. Strong intramolecular N—H⋯N and N—H⋯O and weak intramolecular C—H⋯S hydrogen bonds complete S(5) and S(6) ring motifs, while strong intermolecular N—H⋯O hydrogen bonds interconnect the three independent molecules through R (3) (3)(12) ring motifs. The three-molecule units are in turn linked into polymeric sheets via C—H⋯F and C—H⋯S hydrogen bonds and π–π interactions [centroid–centroid distances in the range 3.520 (2)–3.820 (9) Å]. |
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