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Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II)...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983269/ https://www.ncbi.nlm.nih.gov/pubmed/21587399 http://dx.doi.org/10.1107/S1600536810035919 |
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author | Gao, Zhongjun Wang, Yanbao |
author_facet | Gao, Zhongjun Wang, Yanbao |
author_sort | Gao, Zhongjun |
collection | PubMed |
description | The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II) atom. The Cu(II) atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H⋯O and non-classical C—H⋯O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions. |
format | Text |
id | pubmed-2983269 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29832692010-12-30 Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate Gao, Zhongjun Wang, Yanbao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II) atom. The Cu(II) atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H⋯O and non-classical C—H⋯O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983269/ /pubmed/21587399 http://dx.doi.org/10.1107/S1600536810035919 Text en © Gao and Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Zhongjun Wang, Yanbao Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
title | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
title_full | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
title_fullStr | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
title_full_unstemmed | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
title_short | Aqua{μ-N-[3-(dimethylamino)propyl]-N′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate |
title_sort | aqua{μ-n-[3-(dimethylamino)propyl]-n′-(2-oxidophenyl)oxamidato(3−)}(1,10-phenanthroline)dicopper(ii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983269/ https://www.ncbi.nlm.nih.gov/pubmed/21587399 http://dx.doi.org/10.1107/S1600536810035919 |
work_keys_str_mv | AT gaozhongjun aquamn3dimethylaminopropyln2oxidophenyloxamidato3110phenanthrolinedicopperiinitrate AT wangyanbao aquamn3dimethylaminopropyln2oxidophenyloxamidato3110phenanthrolinedicopperiinitrate |