Cargando…

Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate

The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II)...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Zhongjun, Wang, Yanbao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983269/
https://www.ncbi.nlm.nih.gov/pubmed/21587399
http://dx.doi.org/10.1107/S1600536810035919
_version_ 1782191841019428864
author Gao, Zhongjun
Wang, Yanbao
author_facet Gao, Zhongjun
Wang, Yanbao
author_sort Gao, Zhongjun
collection PubMed
description The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II) atom. The Cu(II) atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H⋯O and non-classical C—H⋯O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions.
format Text
id pubmed-2983269
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29832692010-12-30 Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate Gao, Zhongjun Wang, Yanbao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II) atom. The Cu(II) atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O—H⋯O and non-classical C—H⋯O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983269/ /pubmed/21587399 http://dx.doi.org/10.1107/S1600536810035919 Text en © Gao and Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhongjun
Wang, Yanbao
Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
title Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
title_full Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
title_fullStr Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
title_full_unstemmed Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
title_short Aqua­{μ-N-[3-(dimethyl­amino)­prop­yl]-N′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(II) nitrate
title_sort aqua­{μ-n-[3-(dimethyl­amino)­prop­yl]-n′-(2-oxidophen­yl)oxamidato(3−)}(1,10-phenanthroline)dicopper(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983269/
https://www.ncbi.nlm.nih.gov/pubmed/21587399
http://dx.doi.org/10.1107/S1600536810035919
work_keys_str_mv AT gaozhongjun aquamn3dimethylaminopropyln2oxidophenyloxamidato3110phenanthrolinedicopperiinitrate
AT wangyanbao aquamn3dimethylaminopropyln2oxidophenyloxamidato3110phenanthrolinedicopperiinitrate