2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile

In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo­hexene ring has a sofa conformation. All the substituents in the cyclo­hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N—H⋯O hydrogen bonds, forming a chain extending...

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Detalles Bibliográficos
Autores principales: Ali, A. Jahubar, Athimoolam, S., Bahadur, S. Asath, Raja, V. P. Alex
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983276/
https://www.ncbi.nlm.nih.gov/pubmed/21587572
http://dx.doi.org/10.1107/S1600536810035567
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author Ali, A. Jahubar
Athimoolam, S.
Bahadur, S. Asath
Raja, V. P. Alex
author_facet Ali, A. Jahubar
Athimoolam, S.
Bahadur, S. Asath
Raja, V. P. Alex
author_sort Ali, A. Jahubar
collection PubMed
description In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo­hexene ring has a sofa conformation. All the substituents in the cyclo­hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N—H⋯O hydrogen bonds, forming a chain extending along the b axis and through C—H⋯N and C—H⋯Cl inter­actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding.
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spelling pubmed-29832762010-12-30 2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile Ali, A. Jahubar Athimoolam, S. Bahadur, S. Asath Raja, V. P. Alex Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo­hexene ring has a sofa conformation. All the substituents in the cyclo­hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N—H⋯O hydrogen bonds, forming a chain extending along the b axis and through C—H⋯N and C—H⋯Cl inter­actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983276/ /pubmed/21587572 http://dx.doi.org/10.1107/S1600536810035567 Text en © Ali et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, A. Jahubar
Athimoolam, S.
Bahadur, S. Asath
Raja, V. P. Alex
2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
title 2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
title_full 2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
title_fullStr 2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
title_full_unstemmed 2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
title_short 2-Amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
title_sort 2-amino-6-(2,4-dichloro­phen­yl)-4-oxo-3,5-diphenyl­cyclo­hex-2-enecarbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983276/
https://www.ncbi.nlm.nih.gov/pubmed/21587572
http://dx.doi.org/10.1107/S1600536810035567
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AT bahadursasath 2amino624dichlorophenyl4oxo35diphenylcyclohex2enecarbonitrile
AT rajavpalex 2amino624dichlorophenyl4oxo35diphenylcyclohex2enecarbonitrile

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