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Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)holmium(III)]
In the centrosymmetric title compound, [Ho(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Ho(III) atom is nine-coordinated by seven O atoms from the 3,4-dimethoxyphenylacetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) molecule. The L ligands are coordinated to the Ho(III) ions...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983278/ https://www.ncbi.nlm.nih.gov/pubmed/21587417 http://dx.doi.org/10.1107/S1600536810036408 |
Sumario: | In the centrosymmetric title compound, [Ho(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Ho(III) atom is nine-coordinated by seven O atoms from the 3,4-dimethoxyphenylacetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) molecule. The L ligands are coordinated to the Ho(III) ions in three modes: chelating, bridging and bridging–tridentate. Intramolecular C—H⋯O interactions occur. The crystal packing is stabilized by intermolecular C—H⋯O interactions and weak aromatic π–π interactions between phen molecules and the aromatic rings of the L ligands [centroid–centroid distance = 3.821 (2) Å]. |
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