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Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]

In the centrosymmetric title compound, [Ho(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Ho(III) atom is nine-coordinated by seven O atoms from the 3,4-dimeth­oxy­phenyl­acetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) mol­ecule. The L ligands are coordinated to the Ho(III) ions...

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Detalles Bibliográficos
Autores principales: Zhao, Guo-Liang, Liu, Jia-Lu, Liu, Jian-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983278/
https://www.ncbi.nlm.nih.gov/pubmed/21587417
http://dx.doi.org/10.1107/S1600536810036408
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author Zhao, Guo-Liang
Liu, Jia-Lu
Liu, Jian-Feng
author_facet Zhao, Guo-Liang
Liu, Jia-Lu
Liu, Jian-Feng
author_sort Zhao, Guo-Liang
collection PubMed
description In the centrosymmetric title compound, [Ho(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Ho(III) atom is nine-coordinated by seven O atoms from the 3,4-dimeth­oxy­phenyl­acetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) mol­ecule. The L ligands are coordinated to the Ho(III) ions in three modes: chelating, bridging and bridging–tridentate. Intra­molecular C—H⋯O inter­actions occur. The crystal packing is stabilized by inter­molecular C—H⋯O inter­actions and weak aromatic π–π inter­actions between phen mol­ecules and the aromatic rings of the L ligands [centroid–centroid distance = 3.821 (2) Å].
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spelling pubmed-29832782010-12-30 Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)] Zhao, Guo-Liang Liu, Jia-Lu Liu, Jian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Ho(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Ho(III) atom is nine-coordinated by seven O atoms from the 3,4-dimeth­oxy­phenyl­acetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) mol­ecule. The L ligands are coordinated to the Ho(III) ions in three modes: chelating, bridging and bridging–tridentate. Intra­molecular C—H⋯O inter­actions occur. The crystal packing is stabilized by inter­molecular C—H⋯O inter­actions and weak aromatic π–π inter­actions between phen mol­ecules and the aromatic rings of the L ligands [centroid–centroid distance = 3.821 (2) Å]. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983278/ /pubmed/21587417 http://dx.doi.org/10.1107/S1600536810036408 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Guo-Liang
Liu, Jia-Lu
Liu, Jian-Feng
Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]
title Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]
title_full Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]
title_fullStr Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]
title_full_unstemmed Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]
title_short Tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(III)]
title_sort tetra­kis(μ-3,4-dimeth­oxy­phenyl­acetato)­bis­[(3,4-dimeth­oxy­phenyl­acetato)(1,10-phenanthroline)holmium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983278/
https://www.ncbi.nlm.nih.gov/pubmed/21587417
http://dx.doi.org/10.1107/S1600536810036408
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AT liujianfeng tetrakism34dimethoxyphenylacetatobis34dimethoxyphenylacetato110phenanthrolineholmiumiii