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catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]

In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carb­oxy-5-carboxyl­ate ligand and four O atoms from four water mol­ecules, forming a distorted octa­hedal geometry. The Na(I) atoms are b...

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Detalles Bibliográficos
Autores principales: Liu, Hai-Yan, Liu, Li-Xin, Sha, Jing-Quan, Yu, Lian-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983283/
https://www.ncbi.nlm.nih.gov/pubmed/21587466
http://dx.doi.org/10.1107/S1600536810037384
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author Liu, Hai-Yan
Liu, Li-Xin
Sha, Jing-Quan
Yu, Lian-Sheng
author_facet Liu, Hai-Yan
Liu, Li-Xin
Sha, Jing-Quan
Yu, Lian-Sheng
author_sort Liu, Hai-Yan
collection PubMed
description In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carb­oxy-5-carboxyl­ate ligand and four O atoms from four water mol­ecules, forming a distorted octa­hedal geometry. The Na(I) atoms are bridged by water mol­ecules into a chain structure along [100]. Inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds connect the chains. An intra­molecular O—H⋯O hydrogen bond between the carboxyl­ate groups is observed.
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spelling pubmed-29832832010-12-30 catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O] Liu, Hai-Yan Liu, Li-Xin Sha, Jing-Quan Yu, Lian-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carb­oxy-5-carboxyl­ate ligand and four O atoms from four water mol­ecules, forming a distorted octa­hedal geometry. The Na(I) atoms are bridged by water mol­ecules into a chain structure along [100]. Inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds connect the chains. An intra­molecular O—H⋯O hydrogen bond between the carboxyl­ate groups is observed. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983283/ /pubmed/21587466 http://dx.doi.org/10.1107/S1600536810037384 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Hai-Yan
Liu, Li-Xin
Sha, Jing-Quan
Yu, Lian-Sheng
catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
title catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
title_full catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
title_fullStr catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
title_full_unstemmed catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
title_short catena-Poly[[(5-carb­oxy-2H-1,2,3-triazole-4-carboxyl­ato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
title_sort catena-poly[[(5-carb­oxy-2h-1,2,3-triazole-4-carboxyl­ato-κ(2) n (3),o (4))sodium]-di-μ-aqua-κ(4) o:o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983283/
https://www.ncbi.nlm.nih.gov/pubmed/21587466
http://dx.doi.org/10.1107/S1600536810037384
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