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catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O]
In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carboxy-5-carboxylate ligand and four O atoms from four water molecules, forming a distorted octahedal geometry. The Na(I) atoms are b...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983283/ https://www.ncbi.nlm.nih.gov/pubmed/21587466 http://dx.doi.org/10.1107/S1600536810037384 |
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author | Liu, Hai-Yan Liu, Li-Xin Sha, Jing-Quan Yu, Lian-Sheng |
author_facet | Liu, Hai-Yan Liu, Li-Xin Sha, Jing-Quan Yu, Lian-Sheng |
author_sort | Liu, Hai-Yan |
collection | PubMed |
description | In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carboxy-5-carboxylate ligand and four O atoms from four water molecules, forming a distorted octahedal geometry. The Na(I) atoms are bridged by water molecules into a chain structure along [100]. Intermolecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds connect the chains. An intramolecular O—H⋯O hydrogen bond between the carboxylate groups is observed. |
format | Text |
id | pubmed-2983283 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29832832010-12-30 catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O] Liu, Hai-Yan Liu, Li-Xin Sha, Jing-Quan Yu, Lian-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carboxy-5-carboxylate ligand and four O atoms from four water molecules, forming a distorted octahedal geometry. The Na(I) atoms are bridged by water molecules into a chain structure along [100]. Intermolecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds connect the chains. An intramolecular O—H⋯O hydrogen bond between the carboxylate groups is observed. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983283/ /pubmed/21587466 http://dx.doi.org/10.1107/S1600536810037384 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Hai-Yan Liu, Li-Xin Sha, Jing-Quan Yu, Lian-Sheng catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2) N (3),O (4))sodium]-di-μ-aqua-κ(4) O:O] |
title |
catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2)
N
(3),O
(4))sodium]-di-μ-aqua-κ(4)
O:O] |
title_full |
catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2)
N
(3),O
(4))sodium]-di-μ-aqua-κ(4)
O:O] |
title_fullStr |
catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2)
N
(3),O
(4))sodium]-di-μ-aqua-κ(4)
O:O] |
title_full_unstemmed |
catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2)
N
(3),O
(4))sodium]-di-μ-aqua-κ(4)
O:O] |
title_short |
catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ(2)
N
(3),O
(4))sodium]-di-μ-aqua-κ(4)
O:O] |
title_sort | catena-poly[[(5-carboxy-2h-1,2,3-triazole-4-carboxylato-κ(2)
n
(3),o
(4))sodium]-di-μ-aqua-κ(4)
o:o] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983283/ https://www.ncbi.nlm.nih.gov/pubmed/21587466 http://dx.doi.org/10.1107/S1600536810037384 |
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