Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)

The Mn(II) atom in the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], exhibits an octa­hedral geometry comprising the two O atoms and two N atoms from two 3-amino­pyrazine-2-carboxyl­ate ligands, which act as chelating ligands, and two water mol­ecules. An intra­molecular N—H⋯O hydrogen bond o...

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Detalles Bibliográficos
Autores principales: Zheng, Min-Yan, Wei, Yong-Sheng, Geng, Wei, Fan, Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983285/
https://www.ncbi.nlm.nih.gov/pubmed/21587383
http://dx.doi.org/10.1107/S1600536810034835
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author Zheng, Min-Yan
Wei, Yong-Sheng
Geng, Wei
Fan, Guang
author_facet Zheng, Min-Yan
Wei, Yong-Sheng
Geng, Wei
Fan, Guang
author_sort Zheng, Min-Yan
collection PubMed
description The Mn(II) atom in the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], exhibits an octa­hedral geometry comprising the two O atoms and two N atoms from two 3-amino­pyrazine-2-carboxyl­ate ligands, which act as chelating ligands, and two water mol­ecules. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link adjacent mol­ecules into a three-dimensional network. The mol­ecule lies on a twofold rotation axis.
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spelling pubmed-29832852010-12-30 Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II) Zheng, Min-Yan Wei, Yong-Sheng Geng, Wei Fan, Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) atom in the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], exhibits an octa­hedral geometry comprising the two O atoms and two N atoms from two 3-amino­pyrazine-2-carboxyl­ate ligands, which act as chelating ligands, and two water mol­ecules. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link adjacent mol­ecules into a three-dimensional network. The mol­ecule lies on a twofold rotation axis. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983285/ /pubmed/21587383 http://dx.doi.org/10.1107/S1600536810034835 Text en © Zheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Min-Yan
Wei, Yong-Sheng
Geng, Wei
Fan, Guang
Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)
title Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)
title_full Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)
title_fullStr Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)
title_full_unstemmed Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)
title_short Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­manganese(II)
title_sort bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) n (1),o)diaqua­manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983285/
https://www.ncbi.nlm.nih.gov/pubmed/21587383
http://dx.doi.org/10.1107/S1600536810034835
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