(1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate

The chiral title compound, C(15)H(22)O(5), is an inter­mediate in the total synthesis of biologically active 9,11-secosterols. In the crystal, the cyclo­hexane rings are trans-fused and both adopt chair conformations. In the crystal, mol­ecules are loosely held together in a layer parallel to (100)...

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Detalles Bibliográficos
Autores principales: Aav, Riina, Lippur, Kristin, Lopp, Margus, Werner, Franz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983288/
https://www.ncbi.nlm.nih.gov/pubmed/21587566
http://dx.doi.org/10.1107/S1600536810036639
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author Aav, Riina
Lippur, Kristin
Lopp, Margus
Werner, Franz
author_facet Aav, Riina
Lippur, Kristin
Lopp, Margus
Werner, Franz
author_sort Aav, Riina
collection PubMed
description The chiral title compound, C(15)H(22)O(5), is an inter­mediate in the total synthesis of biologically active 9,11-secosterols. In the crystal, the cyclo­hexane rings are trans-fused and both adopt chair conformations. In the crystal, mol­ecules are loosely held together in a layer parallel to (100) by weak inter­molcular C—H⋯O hydrogen bonds accepted by carbonyl O atoms of the acetyl groups.
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spelling pubmed-29832882010-12-30 (1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate Aav, Riina Lippur, Kristin Lopp, Margus Werner, Franz Acta Crystallogr Sect E Struct Rep Online Organic Papers The chiral title compound, C(15)H(22)O(5), is an inter­mediate in the total synthesis of biologically active 9,11-secosterols. In the crystal, the cyclo­hexane rings are trans-fused and both adopt chair conformations. In the crystal, mol­ecules are loosely held together in a layer parallel to (100) by weak inter­molcular C—H⋯O hydrogen bonds accepted by carbonyl O atoms of the acetyl groups. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983288/ /pubmed/21587566 http://dx.doi.org/10.1107/S1600536810036639 Text en © Aav et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aav, Riina
Lippur, Kristin
Lopp, Margus
Werner, Franz
(1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
title (1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
title_full (1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
title_fullStr (1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
title_full_unstemmed (1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
title_short (1S,2S,6S,9S)-6-Methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
title_sort (1s,2s,6s,9s)-6-methyl-5-oxobicyclo­[4.4.0]decane-2,9-diyl diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983288/
https://www.ncbi.nlm.nih.gov/pubmed/21587566
http://dx.doi.org/10.1107/S1600536810036639
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AT loppmargus 1s2s6s9s6methyl5oxobicyclo440decane29diyldiacetate
AT wernerfranz 1s2s6s9s6methyl5oxobicyclo440decane29diyldiacetate

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