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[2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3) N,N′,N′′]dichloridoiron(II)
In the molecule of the title compound, [FeCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe(II) atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudor...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983294/ https://www.ncbi.nlm.nih.gov/pubmed/21587438 http://dx.doi.org/10.1107/S1600536810037049 |
| _version_ | 1782191847332904960 |
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| author | Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng |
| author_facet | Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng |
| author_sort | Li, Xiao-Ping |
| collection | PubMed |
| description | In the molecule of the title compound, [FeCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe(II) atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938 (11):0.062 (11) ratio. Intermolecular C—H⋯Cl hydrogen bonding occurs in the crystal structure. |
| format | Text |
| id | pubmed-2983294 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29832942010-12-30 [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3) N,N′,N′′]dichloridoiron(II) Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [FeCl(2)(C(25)H(19)N(3))], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe(II) atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938 (11):0.062 (11) ratio. Intermolecular C—H⋯Cl hydrogen bonding occurs in the crystal structure. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983294/ /pubmed/21587438 http://dx.doi.org/10.1107/S1600536810037049 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xiao-Ping Zhao, Jian-She Ng, Seik Weng [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3) N,N′,N′′]dichloridoiron(II) |
| title | [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3)
N,N′,N′′]dichloridoiron(II) |
| title_full | [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3)
N,N′,N′′]dichloridoiron(II) |
| title_fullStr | [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3)
N,N′,N′′]dichloridoiron(II) |
| title_full_unstemmed | [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3)
N,N′,N′′]dichloridoiron(II) |
| title_short | [2,6-Bis(6-methylquinolin-2-yl)pyridine-κ(3)
N,N′,N′′]dichloridoiron(II) |
| title_sort | [2,6-bis(6-methylquinolin-2-yl)pyridine-κ(3)
n,n′,n′′]dichloridoiron(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983294/ https://www.ncbi.nlm.nih.gov/pubmed/21587438 http://dx.doi.org/10.1107/S1600536810037049 |
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