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1,8-Diiodo­anthracene

The mol­ecule of the title compound, C(14)H(8)I(2), an inter­mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich–herringbone arrangement of m...

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Detalles Bibliográficos
Autores principales: Nakanishi, Waka, Hitosugi, Shunpei, Piskareva, Anna, Isobe, Hiroyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983297/
https://www.ncbi.nlm.nih.gov/pubmed/21587509
http://dx.doi.org/10.1107/S1600536810035191
Descripción
Sumario:The mol­ecule of the title compound, C(14)H(8)I(2), an inter­mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich–herringbone arrangement of mol­ecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro­anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra­cenes and chrycenes.