1,8-Diiodo­anthracene

The mol­ecule of the title compound, C(14)H(8)I(2), an inter­mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich–herringbone arrangement of m...

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Detalles Bibliográficos
Autores principales: Nakanishi, Waka, Hitosugi, Shunpei, Piskareva, Anna, Isobe, Hiroyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983297/
https://www.ncbi.nlm.nih.gov/pubmed/21587509
http://dx.doi.org/10.1107/S1600536810035191
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author Nakanishi, Waka
Hitosugi, Shunpei
Piskareva, Anna
Isobe, Hiroyuki
author_facet Nakanishi, Waka
Hitosugi, Shunpei
Piskareva, Anna
Isobe, Hiroyuki
author_sort Nakanishi, Waka
collection PubMed
description The mol­ecule of the title compound, C(14)H(8)I(2), an inter­mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich–herringbone arrangement of mol­ecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro­anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra­cenes and chrycenes.
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spelling pubmed-29832972010-12-30 1,8-Diiodo­anthracene Nakanishi, Waka Hitosugi, Shunpei Piskareva, Anna Isobe, Hiroyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(14)H(8)I(2), an inter­mediate in the synthesis of organic materials, is nearly planar, the maximum deviation from the mean plane being 0.032 (1) Å for the C atoms and 0.082 (2) Å for the I atoms. In the crystal structure, a sandwich–herringbone arrangement of mol­ecules is observed, whereas a columnar π-stacking arrangement has been reported for the chlorinated congener 1,8-dichloro­anthracene. Similar effects of halogen substituents on the modulation of packing arrangements are reported for halogenated aromatic compounds such as tetra­cenes and chrycenes. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983297/ /pubmed/21587509 http://dx.doi.org/10.1107/S1600536810035191 Text en © Nakanishi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nakanishi, Waka
Hitosugi, Shunpei
Piskareva, Anna
Isobe, Hiroyuki
1,8-Diiodo­anthracene
title 1,8-Diiodo­anthracene
title_full 1,8-Diiodo­anthracene
title_fullStr 1,8-Diiodo­anthracene
title_full_unstemmed 1,8-Diiodo­anthracene
title_short 1,8-Diiodo­anthracene
title_sort 1,8-diiodo­anthracene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983297/
https://www.ncbi.nlm.nih.gov/pubmed/21587509
http://dx.doi.org/10.1107/S1600536810035191
work_keys_str_mv AT nakanishiwaka 18diiodoanthracene
AT hitosugishunpei 18diiodoanthracene
AT piskarevaanna 18diiodoanthracene
AT isobehiroyuki 18diiodoanthracene

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