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Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)

In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Inter­molecular C—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the pyridine r...

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Autores principales: Akbarzadeh Torbati, Niloufar, Rezvani, Ali Reza, Safari, Nasser, Saravani, Hamideh, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983300/
https://www.ncbi.nlm.nih.gov/pubmed/21587427
http://dx.doi.org/10.1107/S1600536810036846
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author Akbarzadeh Torbati, Niloufar
Rezvani, Ali Reza
Safari, Nasser
Saravani, Hamideh
Amani, Vahid
author_facet Akbarzadeh Torbati, Niloufar
Rezvani, Ali Reza
Safari, Nasser
Saravani, Hamideh
Amani, Vahid
author_sort Akbarzadeh Torbati, Niloufar
collection PubMed
description In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Inter­molecular C—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid–centroid distances = 3.788 (1) and 3.957 (1) Å] are present in the crystal structure.
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spelling pubmed-29833002010-12-30 Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) Akbarzadeh Torbati, Niloufar Rezvani, Ali Reza Safari, Nasser Saravani, Hamideh Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Inter­molecular C—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid–centroid distances = 3.788 (1) and 3.957 (1) Å] are present in the crystal structure. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983300/ /pubmed/21587427 http://dx.doi.org/10.1107/S1600536810036846 Text en © Akbarzadeh Torbati et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akbarzadeh Torbati, Niloufar
Rezvani, Ali Reza
Safari, Nasser
Saravani, Hamideh
Amani, Vahid
Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_full Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_fullStr Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_full_unstemmed Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_short Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_sort dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) n,n′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983300/
https://www.ncbi.nlm.nih.gov/pubmed/21587427
http://dx.doi.org/10.1107/S1600536810036846
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