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Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Intermolecular C—H⋯Cl hydrogen bonds and π–π stacking interactions between the pyridine r...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983300/ https://www.ncbi.nlm.nih.gov/pubmed/21587427 http://dx.doi.org/10.1107/S1600536810036846 |
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author | Akbarzadeh Torbati, Niloufar Rezvani, Ali Reza Safari, Nasser Saravani, Hamideh Amani, Vahid |
author_facet | Akbarzadeh Torbati, Niloufar Rezvani, Ali Reza Safari, Nasser Saravani, Hamideh Amani, Vahid |
author_sort | Akbarzadeh Torbati, Niloufar |
collection | PubMed |
description | In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Intermolecular C—H⋯Cl hydrogen bonds and π–π stacking interactions between the pyridine rings [centroid–centroid distances = 3.788 (1) and 3.957 (1) Å] are present in the crystal structure. |
format | Text |
id | pubmed-2983300 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833002010-12-30 Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) Akbarzadeh Torbati, Niloufar Rezvani, Ali Reza Safari, Nasser Saravani, Hamideh Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Intermolecular C—H⋯Cl hydrogen bonds and π–π stacking interactions between the pyridine rings [centroid–centroid distances = 3.788 (1) and 3.957 (1) Å] are present in the crystal structure. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983300/ /pubmed/21587427 http://dx.doi.org/10.1107/S1600536810036846 Text en © Akbarzadeh Torbati et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Akbarzadeh Torbati, Niloufar Rezvani, Ali Reza Safari, Nasser Saravani, Hamideh Amani, Vahid Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) |
title | Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
title_full | Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
title_fullStr | Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
title_full_unstemmed | Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
title_short | Dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
title_sort | dichlorido(6,6′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983300/ https://www.ncbi.nlm.nih.gov/pubmed/21587427 http://dx.doi.org/10.1107/S1600536810036846 |
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