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(E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one
In the title compound, C(15)H(12)Cl(2)O(3)S, the prop-2-en-1-one (enone) fragment is almost planar [C—C—C—O = 2.2 (4)°] and it subtends dihedral angles of 11.9 (2) and 11.0 (2)° with the thiophene and benzene rings, respectively. The dihedral angle between the aromatic rings is 3.47 (16)°. In the c...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983303/ https://www.ncbi.nlm.nih.gov/pubmed/21587480 http://dx.doi.org/10.1107/S1600536810035142 |
| _version_ | 1782191849476194304 |
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| author | Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. |
| author_facet | Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. |
| author_sort | Harrison, William T. A. |
| collection | PubMed |
| description | In the title compound, C(15)H(12)Cl(2)O(3)S, the prop-2-en-1-one (enone) fragment is almost planar [C—C—C—O = 2.2 (4)°] and it subtends dihedral angles of 11.9 (2) and 11.0 (2)° with the thiophene and benzene rings, respectively. The dihedral angle between the aromatic rings is 3.47 (16)°. In the crystal, weak C—H⋯O and C—H⋯Cl interactions link the molecules, leading to R (2) (2)(14), R (2) (2)(24) and C(11) supramolecular motifs occurring within the three-dimensional network. Weak aromatic π–π stacking [centroid–centroid separations = 3.6823 (15) and 3.8722 (15) Å] may also help to consolidate the packing. |
| format | Text |
| id | pubmed-2983303 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29833032010-12-30 (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)Cl(2)O(3)S, the prop-2-en-1-one (enone) fragment is almost planar [C—C—C—O = 2.2 (4)°] and it subtends dihedral angles of 11.9 (2) and 11.0 (2)° with the thiophene and benzene rings, respectively. The dihedral angle between the aromatic rings is 3.47 (16)°. In the crystal, weak C—H⋯O and C—H⋯Cl interactions link the molecules, leading to R (2) (2)(14), R (2) (2)(24) and C(11) supramolecular motifs occurring within the three-dimensional network. Weak aromatic π–π stacking [centroid–centroid separations = 3.6823 (15) and 3.8722 (15) Å] may also help to consolidate the packing. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983303/ /pubmed/21587480 http://dx.doi.org/10.1107/S1600536810035142 Text en © Harrison et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Harrison, William T. A. Chidan Kumar, C. S. Yathirajan, H. S. Mayekar, A. N. Narayana, B. (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| title | (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| title_full | (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| title_fullStr | (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| title_full_unstemmed | (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| title_short | (E)-1-(2,5-Dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| title_sort | (e)-1-(2,5-dichloro-3-thienyl)-3-(3,4-dimethoxyphenyl)prop-2-en-1-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983303/ https://www.ncbi.nlm.nih.gov/pubmed/21587480 http://dx.doi.org/10.1107/S1600536810035142 |
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