2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)

In the title compound, C(12)H(13)NO(4)S, a systemic fungicide, the heterocycle adopts a lounge chair conformation and the dihedral angle between the ring planes is 25.8 (2)°. Inter­molecular C—H⋯O hydrogen bonds are noted in the crystal structure. Also observed is a short inter­action of a methyl­en...

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Detalles Bibliográficos
Autores principales: Brown, J. Emery, Baughman, Russell G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983306/
https://www.ncbi.nlm.nih.gov/pubmed/21587625
http://dx.doi.org/10.1107/S1600536810037669
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author Brown, J. Emery
Baughman, Russell G.
author_facet Brown, J. Emery
Baughman, Russell G.
author_sort Brown, J. Emery
collection PubMed
description In the title compound, C(12)H(13)NO(4)S, a systemic fungicide, the heterocycle adopts a lounge chair conformation and the dihedral angle between the ring planes is 25.8 (2)°. Inter­molecular C—H⋯O hydrogen bonds are noted in the crystal structure. Also observed is a short inter­action of a methyl­ene hydrogen atom with the π-electron system of a phenyl ring in an adjacent mol­ecule.
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spelling pubmed-29833062010-12-30 2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin) Brown, J. Emery Baughman, Russell G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(13)NO(4)S, a systemic fungicide, the heterocycle adopts a lounge chair conformation and the dihedral angle between the ring planes is 25.8 (2)°. Inter­molecular C—H⋯O hydrogen bonds are noted in the crystal structure. Also observed is a short inter­action of a methyl­ene hydrogen atom with the π-electron system of a phenyl ring in an adjacent mol­ecule. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983306/ /pubmed/21587625 http://dx.doi.org/10.1107/S1600536810037669 Text en © Brown and Baughman 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Brown, J. Emery
Baughman, Russell G.
2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)
title 2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)
title_full 2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)
title_fullStr 2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)
title_full_unstemmed 2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)
title_short 2-Methyl-4,4-dioxo-N-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (Oxycarboxin)
title_sort 2-methyl-4,4-dioxo-n-phenyl-5,6-di­hydro-1,4-oxathiine-3-carboxamide (oxycarboxin)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983306/
https://www.ncbi.nlm.nih.gov/pubmed/21587625
http://dx.doi.org/10.1107/S1600536810037669
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