Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)

In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P—Au—Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, wit...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Tariq, Abu, Ghani, Syed Sauban, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983311/
https://www.ncbi.nlm.nih.gov/pubmed/21587375
http://dx.doi.org/10.1107/S1600536810034896
Descripción
Sumario:In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P—Au—Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591 (11):0.409 (11) and 0.730 (12):0.270 (12). In the crystal structure, mol­ecules are linked into a three-dimensional network by inter­molecular C—H⋯Cl and C—H⋯F hydrogen bonds.

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