Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)

In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P—Au—Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, wit...

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Autores principales: Shawkataly, Omar bin, Tariq, Abu, Ghani, Syed Sauban, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983311/
https://www.ncbi.nlm.nih.gov/pubmed/21587375
http://dx.doi.org/10.1107/S1600536810034896
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author Shawkataly, Omar bin
Tariq, Abu
Ghani, Syed Sauban
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Tariq, Abu
Ghani, Syed Sauban
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P—Au—Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591 (11):0.409 (11) and 0.730 (12):0.270 (12). In the crystal structure, mol­ecules are linked into a three-dimensional network by inter­molecular C—H⋯Cl and C—H⋯F hydrogen bonds.
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spelling pubmed-29833112010-12-30 Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I) Shawkataly, Omar bin Tariq, Abu Ghani, Syed Sauban Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P—Au—Cl unit is nearly linear, with an angle of 178.13 (5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7 (3), 84.4 (3) and 77.4 (3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591 (11):0.409 (11) and 0.730 (12):0.270 (12). In the crystal structure, mol­ecules are linked into a three-dimensional network by inter­molecular C—H⋯Cl and C—H⋯F hydrogen bonds. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983311/ /pubmed/21587375 http://dx.doi.org/10.1107/S1600536810034896 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Tariq, Abu
Ghani, Syed Sauban
Yeap, Chin Sing
Fun, Hoong-Kun
Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)
title Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)
title_full Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)
title_fullStr Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)
title_full_unstemmed Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)
title_short Chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(I)
title_sort chlorido[tris­(3-fluoro­phen­yl)phosphine]gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983311/
https://www.ncbi.nlm.nih.gov/pubmed/21587375
http://dx.doi.org/10.1107/S1600536810034896
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AT ghanisyedsauban chloridotris3fluorophenylphosphinegoldi
AT yeapchinsing chloridotris3fluorophenylphosphinegoldi
AT funhoongkun chloridotris3fluorophenylphosphinegoldi

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