Undeca­carbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris­(2-chloro­eth­yl) phosphite-1κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axia...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Ghani, Syed Sauban, Jothiramalingam, Rajabathar, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983316/
https://www.ncbi.nlm.nih.gov/pubmed/21587355
http://dx.doi.org/10.1107/S1600536810033891
Descripción
Sumario:In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the mol­ecules are linked into a one-dimensional column along [100] by inter­molecular C—H⋯O hydrogen bonds.

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